سنتز اکسیدگرافن آلایش‌شده مضاعف با عصاره‌ سیر و کاتیون‌های مس برای استفاده در پوشش‌‌های ضدباکتری

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه پژوهشی پوشش‌های سطح و خوردگی، پژوهشگاه رنگ، تهران، ایران، صندوق پستی: 654-167654

2 شرکت اطلس پوشش محافظ، تهران، ایران، صندوق پستی: 841-1668815

3 آزمایشگاه نانومواد و نانوکامپوزیت پلیمری، دانشکده مهندسی، دانشگاه بریتیش کلمبیا، کانادا

چکیده

علی‌رغم تلاش‌های خستگی‌ناپذیر در زمینه‌ کاوش داروها و عوامل ضدباکتری، همواره دست‌یابی به خاصیت ضدباکتری بهبودیافته و به‌حداقل رساندن مواد مضر امری چالش برانگیز بوده‌است. نظر به خواص ضدباکتری اعجاب برانگیز عصاره‌ی سیر، در این پژوهش به‌جای استفاده از عوامل احیاکننده ‌خطرناک از عصاره‌ی سیر با هدف احیا و آلایش اکسید گرافن به‌صورت هم‌زمان استفاده گردید. به منظوراحیا/ آلایش اکسید گرافن روش گرمابی به‌کار گرفته شد. در ادامه، کاتیون‌های مس بر روی بستر اکسید گرافنی آلایش‌شده با عصاره سیر بارگذاری شد. سنتز موفقیت‌آمیز محصول توسط آزمون طیف‌سنجی تبدیل فوریه زیر قرمز تایید شد. جهت تایید آلایش اکسید گرافن توسط عصاره سیر از آزمون طیف‌سنجی فوتوالکترون پرتو ایکس استفاده شد. همچنین براساس نتایج آزمون طیف سنجی فوتوالکترون پرتو ایکس میزان بارگذاری دو عنصر گوگرد و نیتروژن به ترتیب برابر با 1.4 درصد و 1.0 درصد گزارش شد. نتایج استفاده از اکسید گرافن آلایش‌شده مضاعف در پوشش آب‌پایه اکریلیکی بر روی دیوارپوش پی‌وی‌سی نشان داد که میزان رشد عوامل باکتریایی با گذشت 6 ساعت در حدود 100 درصد کاهش می‌یابد.

کلیدواژه‌ها

عنوان مقاله [English]

Synthesis of Double-doped Graphene Oxide with Garlic Extract and Cu Cations for Application in Anti-bacterial Coatings

نویسندگان [English]

  • S. Akbaripoor Tafreshi Nejad 1
  • E. Alibakhshi 2
  • B. Ramezanzadeh 1
  • S. A. Haddadi 3
  • M. Arjmand 3
  • M. Mahdavian 1
1 Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
2 Atlas Protecting Coating, P. O. Box: 1668815-841, Tehran, Iran
3 Nanomaterials and Polymer Nanocomposites Laboratory, School of Engineering, University of British Columbia, Kelowna, BC, V1V 1V7 Canada
چکیده [English]

Notwithstanding the indefatigable endeavor to explore antibacterial drugs and agents, achieving improved antibacterial properties and minimizing hazardous matters has always been challenging. Garlic extract was utilized to reduce and dope graphene oxide simultaneously, considering the astonishing antibacterial characteristics of garlic extract instead of using dangerous reducing agents. A hydrothermal method was used to reduce/ dope graphene oxide. Copper cations were also loaded on the graphene oxide nanosheets doped with garlic extract. The successful synthesis of the products was confirmed by Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy was used to affirm the doping of graphene oxide using garlic extract. Furthermore, according to the results obtained from X-ray photoelectron spectroscopy, the atomic percentage of S and N elements was 1.4 % and 1 %, respectively. The result revealed that double-doped graphene oxide in water base acrylic coating on PVC panels showed a 100 percent decrease in the growth of bacteria after 6 hours.

کلیدواژه‌ها [English]

  • Graphene oxide
  • Garlic extract
  • Reduction
  • Antibacterial
  • Acrylic
  • PVC panel

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