حذف موثر رنگ اسید آبی 113 از پساب‌های صنعتی با استفاده از منعقدکننده طبیعی و Fe3O4/MnO2 در سیستم تصفیه ترکیبی انعقاد/ ازن‌زنی کاتالیزوری

نوع مقاله : مقاله پژوهشی

نویسندگان

گروه شیمی، دانشکده علوم پایه، دانشگاه گیلان، رشت، ایران، صندوق پستی: ۱۹۱۴۱- ۴۱۳۳۵

چکیده

در این مطالعه، از روش تصفیه ترکیبی انعقاد با منعقدکننده طبیعی و ازن‌زنی کاتالیزوری برای حذف رنگ اسید آبی 113 از محلول رنگی استفاده شد. در مرحله اول، موسیلاژ حاصل از بذر گیاه بالنگو برای پیش تصفیه محلول حاوی رنگ مورد استفاده قرار گرفت. در مرحله دوم برای حذف کامل رنگ از روش ازن زنی کاتالیزوری با نانوکاتالیزور Fe3O4/MnO2 استفاده شد. برای آنالیز و بهینه‌سازی پارامترهای هر دو فرآیند از روش سطح پاسخ با طراحی آزمایش باکس-بنکن استفاده شد. بیشینه حذف رنگ با روش انعقاد-لخته‌سازی 56 درصد بود که در شرایط بهینه pH برابر با 5.2، زمان 20 دقیقه و مقدار ppm 100 منعقدکننده به دست آمد. در فرآیند ازن‌زنی کاتالیزوری در pH 5.3، 18 میلی‌گرم نانوکامپوزیت، g.L-1.h-1 0.2 ازن و 12 دقیقه حذف تقریبا کامل رنگ به دست آمد. نتایج نشان می‌دهد که روش تصفیه ترکیبی عملکرد بسیار خوبی را در حذف رنگ نشان می‌دهد و می‌تواند جهت حذف سایر آلاینده‌های آلی از پساب‌های صنعتی نیز مورد استفاده قرار گیرد.

کلیدواژه‌ها

عنوان مقاله [English]

Effective Removal of Acid Blue 113 Dye from Industrial Effluents Using Natural Coagulant and Fe3O4/MnO2 in Coagulation/Ozonation Combined Treatment System

نویسندگان [English]

  • Seyed Mehdi Pourmoheb Hosseini
  • Naz Chaibakhsh
Department of Chemistry, Faculty of Sciences, University of Guilan, P.O.Box: 41996-13776, Rasht, Iran
چکیده [English]

In this study, the combined treatment method of coagulation with natural coagulant and catalytic ozonation was used to remove Acid Blue 113 dye from the dye solution. In the first stage, the mucilage extracted from the Balangu (Lallemantia royleana) plant seeds was used to pre-treat the dye-containing solution. In the second stage, catalytic ozonation with Fe3O4/MnO2 nanocatalyst was used to completely remove the dye. Response surface methodology with Box-Benken design was used to analyze and optimize the parameters of both processes. Maximum dye removal by the coagulation-flocculation process was 56%, which was obtained in the optimal conditions of pH 5.2, 20 min, and a coagulant amount of 100 ppm. In the catalytic ozonation process at pH 3.5, 18 mg of the nanocomposite, 0.2 g.L-1.h-1 of ozone, and 12 min, almost complete removal of dye was achieved. The results indicate that the combined treatment method performs excellent dye removal and can also be used to remove other organic pollutants from industrial effluents.

کلیدواژه‌ها [English]

  • Mucilage
  • Acid Blue 113
  • Wastewater treatment
  • Coagulation
  • Catalytic ozonation

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