مطالعه تخریب فراصوتی کاتالیزور نوری رنگزای اسید قرمز 37 با استفاده از نانوکامپوزیت@Zeolite MgO/g-C3N4

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه مهندسی شیمی، دانشکده فنی و مهندسی، واحد اهر، دانشگاه آزاد اسلامی، اهر، ایران، صندوق پستی: 14515/775

2 گروه شیمی، دانشکده علوم پایه، واحد اهر، دانشگاه آزاد اسلامی، اهر، ایران، صندوق پستی: 14515/775

چکیده

هدف از این تحقیق بررسی تخریب فراصوتی کاتالیزور نوری رنگزا اسید قرمز 37(AR37)  با استفاده از نانوکامپوزیت MgO/g-C3N4@Zeolite بود. در این تحقیق، نانوکامپوزیت MgO/g-C3N4/Zeolite سنتز شده و با دستگاه‌های پراش پرتو ایکس (XRD)، طیف‌سنجی تبدیل فوریه زیر ‌قرمز (FTIR)، میکروسکوپ الکترونی روبشی گسیل میدانی (FESEM)، اسپکتروسکوپی پراش انرژی (EDS) و Dot mapping شناسایی شد. نانوکامپوزیت سنتز شده به‌عنوان کاتالیزور نوری برای تخریب رنگ اسید قرمز 37 در محلول‌های آب تحت نور UV و امواج فراصوت به کار رفت. عوامل مؤثر بر فرآیند حذف رنگ شامل زمان واکنش، pH محلول، غلظت اولیه رنگ و مقدار نانوکامپوزیت بررسی شدند. نتایج نشان داد که درصد حذف رنگ با افزایش زمان واکنش، pH محلول و مقدار نانوکامپوزیت افزایش و با افزایش غلظت اولیه رنگ کاهش می‌یابد. بیشینه درصد حذف در زمان واکنش 50 دقیقه،pH  محلول 10، غلظت اولیه رنگ 10 میلی‌گرم بر لیتر و مقدار کاتالیزور 0.25 گرم بر 500 میلی‌لیتر، به 72.36 درصد رسید.

کلیدواژه‌ها

عنوان مقاله [English]

Study of Sonophotocatalytic Degradation of Acid Red 37 Dye Using MgO/g-C3N4@Zeolite Nanocomposite

نویسندگان [English]

  • E. Fathi 1
  • F. Derakhshan fard 1
  • P. Gharbani 2
  • Z. Ghazi Tabatabaei 2
1 Department of Chemical Engineering, Ahar Branch, Islamic Azad University, P.O. Box: 775/14515, Ahar, Iran
2 Department of Chemistry, Ahar Branch, Islamic Azad University, P.O. Box: 775/14515, Ahar, Iran
چکیده [English]

This research aimed to study sonophotocatalytic degradation of Reactive Orange 16 dye (RO16) by MgO/g-C3N4@Zeolite nanocomposite. MgO/g-C3N4/Zeolite nanocomposite was synthesized and characterized using the following methods: X-ray diffraction (XRD), fourier-transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS) and dot mapping. The synthesized nanocomposite was used as a photocatalyst to degrade RO16 dye aqueous solution. The tests were performed under UV light and ultrasound irradiation. The effect of main factors on the removal of the dye, such as reaction time, solution pH, initial dye concentration, and nanocomposite dosage, were investigated. Results demonstrated that the percentage of dye removal was increased by raising the reaction time, the solution pH, and nanocomposite dosage and decreased by increasing the initial dye concentration. The maximum removal percentage reached 72.36 % at a reaction time of 50 min., pH of 10, initial dye concentration of 10 mg/L, and nanocomposite dosage of 0.25 g/500mL.

کلیدواژه‌ها [English]

  • MgO/g-C3N4@Zeolite nanocomposite
  • Sonophotocatalyst
  • Acid Red 37 dye
  • degradation

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