استفاده از نانوکامپوزیت CuO/Cu2O برای حذف رنگ متیل نارنجی از محلول آبی

نوع مقاله : مقاله پژوهشی

نویسنده

دانشکده علوم، دانشگاه گلستان، گرگان، ایران، صندوق پستی: 155

چکیده

نانوکامپوزیت CuO/Cu2O توسط روش تخریب گرمایی مخلوطی از مس(II) استات تک آبه و پلی­(وینیل­الکل) و به کمک روش‌های طیف‌سنجی تبدیل فوریه زیر قرمز (FT-IR)، پراش پرتو ایکس (XRD) و میکروسکوپ الکترونی عبوری (TEM) شناسایی شدند. پیک‌های ظاهر شده در طیف FT-IR، و هم‌چنین در الگوی XRD، سنتز نانوکامپوزیت CuO/Cu2O را تایید می­کنند. تصویر TEM نشان می‌دهد که نانوذرات کلوخه‌ای می‌باشند. نانوکامپوزیت CuO/Cu2O به­عنوان یک جاذب جدید برای حذف رنگ متیل نارنجی از محلول آبی مورد استفاده قرار گرفت. نتایج حذف رنگ نشان می‌دهند که غلظت اولیه رنگ تاثیری بر بازده حذف ندارد، و بازده حذف رنگ در محدوده 97 درصد ثابت باقی می­ماند. اما با افزایش pH از 2 تا 8 مقدار حذف رنگ زیاد می‌شود، که بیشترین بازده در pH برابر 8 به­دست آمد. پس از آن با افزایش pH و رسیدن به 12 حذف رنگ به حدود 11 درصد کاهش پیدا می‌کند. همچنین با افزایش مقدار جاذب از 5  به 20 میلی­گرم و افزایش مدت زمان تماس از 5 به 30 دقیقه کارایی جذب رنگ به حدود 99.5 درصد افزایش پیدا کرده است.

کلیدواژه‌ها

عنوان مقاله [English]

Use of CuO/Cu2O Nanocomposite to Removal of Methyl Orange Dye from Aqueous Solution

نویسنده [English]

  • Aliakbar Dehno Khalaji
Faculty of Science, Golestan University, P.O. Box: 155, Gorgan, Iran
چکیده [English]

Thermal decomposition of copper (II) acetate monohydrate and polyvinyl alcohol results in CuO/Cu2O nanocomposite synthesis. It was characterized by FT-IR, XRD, and TEM techniques. The peaks appeared in the FT-IR spectrum and the XRD pattern, confirming the CuO/Cu2O nanocomposite preparation. The TEM image shows that the particles are agglomerated. The CuO/Cu2O nanocomposite was used as a new adsorbent to remove methyl orange dye from the aqueous solution. The results of the dye removal study show that initial dye concentration has no effect on the removal percentage, and the dye removal percentage was constant at about 97%. However, dye removal increased with an increase in pH from 2 to 8, with the highest yield occurring at pH equal to 8. After increasing the pH and reaching 12, the removal percentage has been reduced. The dye removal efficiency increases to 99.5% by increasing the amount of adsorbent from 5 to 20 mg and by increasing the contact time from 5 to 30 minutes.

کلیدواژه‌ها [English]

  • Nanocomposite
  • CuO/Cu2O
  • Thermal decomposition
  • Adsorbent
  • Adsorption
  • Methyl orange

مراجع

  1. S. M. Ibrahim, A. A. Badawy, H. A. Essawy, Improvement of dyes removal from aqueous solution by Nanosized cobalt ferrite treated with humic acid during coprecipitation. J. Nanostruct. Chem. 9 (2019), 281-298.
  2. Y. Zhou, J. Lu, Y. Zhou, Y. Liu, Recent advances for dyes removal using novel adsorbents: A review. Environ.. Pollut. 252 (2019), 352-365.
  3. Y. Haldoraj, J. J. Shim, An efficient removal of methyl orange dye from aqueous solution by adsorption onto chitosan/MgO composite: A novel reusable adsorption. Appl. Surface Sci. 292 (2014), 447-453.
  4. I. Ali, I. Burakova, E. Galunin, A. Burakov, E. Mkrtchyan, A. Melezhik, High-speed and high-capacity removal of methyl orange and malachite green in water using newly developed mesoporous carbon: kinetic and isotherm studies. ACS Omega. 4 (2019), 19293-19306.
  5. R. Gong, J. Ye, W. Dai, X. Yan, J. Hu, X. Hu. Adsorptive removal of methyl orange and methylene blue from aqueous solution with finger-citron-residue-based activated carbon. indust. Eng. Chem. Res. 52 (2013), 14297-14303.
  6. W. Wu, T. Yao, Y. Xiang, H. Zou, Y. Zhou, Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial. Dalton Trans. 49 (2020), 5722-5729.
  7. L. Liu, Z.Y. Gao, X.P. Su, X. Chen, L. Jiang, J. M. Yao, Adsorption removal of dyes from single and binary solutions using a cellulose-based bioadsorbent. ACS Sustain. Chem. Eng. 3 (2015), 432-442.
  8. A. Ahmad, S. H. Mohd-Setapar, C. S. Chuong, A. Khatoon, W. A. Wani, R. Kumar, Recent advances in new generation dye removal technologies: novel search for approaches to reprocess wastewater. RSC Adv. 5 (2015), 30801-30818.
  9. Z. Maderova, E. Baldikova, K. Pospiskova, I. Safarik, M. Safarikova, Removal of dyes by adsorption on magnetically modified activated sludge. Int. J. Environ. Sci. Technol. 13 (2016), 1653-1664.
  10. M. Bahgat, A. A. Farghali, W. El Rouby, M. Khedr, M. Y. Mohassab-Ahmed, Adsorption of methyl green dye onto multi-walled carbon nanotube decorated with Ni nanoferrite. Appl. Nanosci. 3 (2013), 251-261.
  11. Rahmi, Isamturrahmi, I. Mustafa, Methylene blue removal from water using H2SO4 crosslinked magnetic chitosan nanocomposite beads. J. 144 (2019), 397-402.
  12. T. Liu, Y. Zheng, A. Wang, Enhanced adsorption of methylene blue from aqueous solution by chitosan-g-poly(acrylic acid)/vermiculite hydrogel composites. J. Environ. Sci. 22 (2010), 486-493.
  13. P. Sharma, B. K. Saikia, M. R. Das, Removal of methyl green dye molecule from aqueous system using reduced grapheme oxide as an efficient adsorbent: Kinetics, isotherm, and thermodynamic parameters. Coll. Surface A: Physicochem. Eng. Aspects. 457 (2014), 125-133.
  14. S. Cinar, U. H. Kaynar, T. Aydemir, S. C. Kaynar, M. Ayvacikli. An efficient removal of RB5 from aqueous solution by adsorption onto nano-ZnO/chitosan composite beads. Int. J. Biol. Macromol. 96 (2017), 459-465.
  15. U. Habiba, T. A. Siddique, J. J. L. Lee, T. C. Joo, B. C. Ang, A. M. Afifi, Adsorption study of methyl orange by chitosan/ polyvinyl alcohol/zeolite electrospun composite nanofibrous membrane. Carbohydr. Polym. 191 (2018), 79-85.
  16. F. C. Tsai, N. Ma, T. C. Chiang, L. C. Tsai, J. J. Shi, Y. Xia, T. Jiang, S. K. Su, F. S. Chuang, Adsoptive removal of methyl orange from aqueous solution with crosslinking chitosan microspheres. J. Water. Process Eng. 1 (2014), 2-7.
  17. L. Obeid, A. Bee, D. Talbot, S. B. Jaafar, V. Dupuis, S. Abramson, V. Cabuil, M. Welschbillig, Chitosan/maghemite composite: A magsorbent for the adsorption of methyl orange. J. Coll. Interface Sci. 410 (2013) 52-58.
  18. L. Zhai, Z. Bai, Y. Zhu, B. Wang, W. Luo, Fabrication of chitosan microspheres for efficient adsorption of methyl orange. Chin. J. Chem. Eng. 26 (2018), 657-666.
  19. S. Sobhnardakani, R. Zandipak, Removal of methyl orange dye from aqueous solutions using NiFe2O4 nanoparticles: Equilibrium and kinetic studies. Iran. J. Health. Environ. 9 (2016), 247-258.
  20. S. H. Mortazavi Milani, A. A. Sabbagh Alvani, R. Salimi, H. Sameie, The study of methods for the degradation of organic dyes by photocatalytic nanoparticles using plasmonic property. J. Stud. Color World. 9(2) (2019), 1-8.
  21. M. Ghaemizade, M. Khajeh Mehrizi, Application of photocatalysts and their effective parameters in the treatment of colored wastewaters. J. Stud. Color World 9(2) (2019), 9-20.
  22. A. Soraya Keshtiban, S. M. Seyedahmadian, B. Habibi, K. Farhadi, An Electrospun Zein/Graphene Oxide Nanofibrous Composite: Typical Application as a New Biopolymeric Adsorbent in Removal of Methylene Blue and Malachite Green Dyes from Aqueous Media. Prog. Color Colorants Coat. 14 (2021), 55-65
  23. M. Maghsoudi, S. khameneh Asl, Review on modification methods of TiO2 nanotubes for photocatalytic degradation of dyes. J. Studies Color World. 9(2019), 21-29.
  24. M. Golmohammadi, A. A. Sabbagh Alvani, H. Sameie, R. Salimi, Characterization of photocatalytic nanocomposites contains reduced graphene oxide and polymeric membrane for dye degradation purpose. J. Studies Color World. 9(2019), 13-22.
  25. S. M. Seyedaahmadian, A. R. Amani-Ghadim, F. Bipir, Synthesize of metal organic frameworks based on the titanium and investigations of its activity in photocatalytic removal of reactive blue 19 dye from aqueous solution. J. Color Sci. Tech. 13 (2019), 253-265.
  26. Saruchi, P. Thakur, V. Kumar, Kinetics and thermodynamic studies for removal of methylene blue dye by biosynthesize copper oxide nanoparticles and its antibacterial activity. Environ. Heal. Sci. Eng. 17 (2019), 367-376.
  27. G. Mustafa, H. Tahir, M. Sultan, N. Akhtar, Synthesis and characterization of cupric oxide (CuO) nanoparticles and their application for the removal of dyes. Afr. J. Biotech. 12 (2013), 6650-6660.
  28. K. Sahu, J. Singh, S. Mohapatra, Photocatalytic and catalytic removal of toxic pollutants from water using CuO nanosheets. J. Mater. Sci. Mater. Elect. 30 (2019), 6088-6099.
  29. P. K. Raul, S. Senapati, A. K. Sahoo, I. M. Umlong, R. R. Devi, A. J. Thakur, CuO nanorods: a potential and efficient adsorbent in water purification. RSC Adv. 4 (2014), 40580-40587.
  30. L. Zhang, Z. Cui, Q. Wu, D. Guo, Y. Xu, L. Guo, Cu2O–CuO composite microframes with well-designed micro/nano structures fabricated via controllable etching of Cu2O microcubes for CO gas sensors. Cryst. Eng. Comm. 15 (2013) 7462-7467.
  31. N. Lu, C. Shao, X. Li, T. Shen, M. Zhang, F. Miao, CuO/Cu2O nanofibers as electrode materials for non-enzymatic glucose sensors with improved sensitivity. RSC Adv. 4 (2014), 31056-31061.
  32. Y. Yang, H. Dong, Y. Wang, Y. Wang, N. Liu, D. Wang, A facile synthesis for porous CuO/Cu2O composites derived from MOFs and their superior catalytic performance for CO oxidation. Inorg. Chem. Commun. 86 (2017(, 74-77.
  33. J. Lv, C. Kong, Y. Xu, Z. Yang, X. Zhang, S. Yang, et al. Facile synthesis of novel CuO/Cu2O nanosheets on copper foil for high sensitive nonenzymatic glucose biosensor. Sens. Act. B: Chem. 248 (2017), 630-638.
  34. Y. Yu, Y. Gao, F. Z. Chen, G. C. Fan, D. M. Han, C. Wang, Fast electrochemical deposition of CuO/Cu2O heterojunction photoelectrode: Preparation and application for rapid cathodic photoelectrochemical detection of L-cysteine. Sens. Act. B: Chem. 290 (2019), 312-317.
  35. B. Sun, H. Li, X. Li, X. Liu, C. Zhang, H. Xu, X.S. Zhao, Degradation of Organic Dyes over Fenton-Like Cu2O−Cu/C Catalysts. Ind. Eng. Chem. Res. 57 (2018), 14011-14021.
  36. D. Jiang, J. Xue, L. Wu, W. Zhou, Y. Zhang, X. Li, Photocatalytic performance enhancement of CuO/Cu2O heterostructures for photodegradation of organic dyes: Effects of CuO morphology. Appl. Catal. B: Environ. 211 (2017), 199–204.
  37. E. Bazrafshan, F. Kord Mostafapour, Evaluation of color removal of methylene blue from aqueous solutions using plant stem ash of Persica. J. North Khorasan Uni. Med. Sci. 4 (2012), 523-532.
  38. G. Yuvaraja, D. Y. Chen, J. L. Pathak, J. Long, M. V. Subbaiah, J. C. Wen, C. L. Pan, Preparation of novel aminated chitosan schiff’s base derivative for the removal of methyl orange dye from aqueous environment and its biological applications. Int. J. Biol. Macromol. 146 (2020), 1100-1110.
  39. A. Davoudi Rad, Z. Hejri, S. Ramezanian Bajgiran, Adsorption optimization of reactive red 120 dye from aqueous media using chitosan-coated magnetically nanoparticles. J. Environ. Water Eng. 5 (2019), 47-57.
  40. A. Homayonfard, M. Miralinaghi, R. Haji Seyed Mohammad Shirazi, E. Moniri, Removal of Cd (II) ion from aqueous solution using nickel ferrite magnetic nanoparticles cross–linked chitosan. J. Water Wastewater, 31 (2020) 112-127.
  41. A. Shokouhi Rad, The synthesis of polyaniline/Fe3O4 to removal of lead ions from water and wastewater samples. J. Water Wastewater, 31 (2020), 169-183.

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