حذف و اندازه‌گیری رنگ بروموکروزول بنفش در نمونه‌های آبی توسط روش استخراج فاز جامد پخشی با نانولوله‌کربنی مغناطیسی اصلاح شده توسط بتاسیکلودکسترین

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشکده علوم پایه، گروه شیمی، دانشگاه آزاد اسلامی، واحد ورامین –پیشوا

2 دانشکده علوم پایه، گروه شیمی، دانشگاه آزاد اسلامی، واحد ورامین –پیشوا

چکیده

این مطالعه به بررسی پیش تغلیظ، تعیین و حذف مقادیر اندک پساب‌های رنگی از رنگ بروموکروزول بنفش در نمونه‌های گوناگون آبی پرداخته است. در این تحقیق روش جدیدی از استخراج فاز جامد در نمونه‌های آبی بوسیله نانولوله‌های کربنی مغناطیسی اصلاح شده با بتاسیکلودکسترین انجام شده است. روش ارائه شده ارزان، آسان و سریع می‌باشد و با بسیاری از روش‌های دستگاهی موجود نیز مطابقت دارد. مشخصه‌های استخراج بروموکروزول بنفش از نمونه آبی شامل اثر حلال آلی واجذب کننده، pH بهینه (9=pH)، زمان استخراج، سرعت هم‌زدن، حجم فاز دهنده مورد مطالعه قرار گرفته است. روش ذکر شده از مزایای بسیاری مانند؛ زمان کوتاه استخراج، مصرف کم حلال‌های آلی، حذف اثر آزمایشات قبلی، حد تشخیص پایین و عامل تغلیظ بالا برخوردارمی‌باشد. عامل تغلیظ 14.3 واحد تشخیص برای رنگ بروموکروزول بنفش به ترتیب  µg/l4.8 به دست آمده است. دامنه خطی روش بین mg/l 20-0.1 و انحراف استاندارد نسبی برای بروموکروزول بنفش 4.65 درصد به دست آمده است.

کلیدواژه‌ها

عنوان مقاله [English]

Removal and measurement of bromocresol purple dye in aqueous samples by β-cyclodextrin-modified magnetic carbon nanotube with dispersive solid-phase extraction technique

نویسندگان [English]

  • ali moghimi 1
  • Milad Abniki 2
1 Department of Chemistry, Varamin-Pishva Branch, Islamic Azad University, Varamin, Iran
2 Department of Chemistry, Varamin-Pishva Branch, Islamic Azad University, Varamin, Iran
چکیده [English]

This study investigated the pre-concentration, determination and removal of small amounts of colored effluents from bromocresol purple dye in various aqueous samples. In this research, a new method of solid phase extraction in aqueous samples has been performed by magnetic carbon nanotubes modified with β-cyclodextrin. The proposed method is cheap, easy and fast and is compatible with many existing device methods. Parameters of extraction of bromocresol purple from an aqueous sample including the effect of organic and desorbent solvent, optimum pH (pH = 9), extraction time, stirring speed, volume of phase giver were studied. The mentioned technique has many advantages such as; It has a short extraction time, low consumption of organic solvents, elimination of the effect of previous tests, low detection limit and high concentration factor. Concentration factor of 14.3 and detection limit for bromocresol purple dye was 4.8 μg / L, respectively. The linear range of method between 0.1-20 mg / L and the relative standard deviation for bromocresol purple was 4.65%.

کلیدواژه‌ها [English]

  • Bromocresol purple
  • Solid-phase extraction
  • β-cyclodextrin
  • UV-Vis spectrophotometry
  • Colored effluent

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