سنتز و کاربرد نانوکامپوزیت حاوی چارچوب آلی- فلزی و نانوذرات مغناطیسی در بستر سیلیکا برای رنگبری متیلن آبی

نوع مقاله : مقاله پژوهشی

نویسندگان

گروه پژوهشی نانوفناوری رنگ، پژوهشگاه رنگ،‌ تهران، ایران، صندوق پستی: 654-16765

چکیده

در این پژوهش نانو کامپوزیت چارچوب آلی- فلزی مغناطیسی (NiFe2O4@SiO2@HKUST-1) با نسبت وزنی نیکل فریت به بستر سیلیکا (90-10) به روش خودآرایی درجا سنتز و شناسایی شد. تشکیل فاز، نوع پیوندهای تشکیل شده، شکل ظاهری و اندازه بلورک‌‌ها، خاصیت مغناطیسی و اندازه مساحت سطح ویژه آ‌‌ن‌ها توسط آزمون‌های طیف‌سنجی زیر قرمز (FT-IR)، تفرق پرتو ایکس (XRD)، میکروسکوپ الکترونی روبشی (SEM)، آزمون مغناطیس‌سنج نمونه ارتعاشی (VSM) و آزمون اندازه‌گیری سطح ویژه (BET) مورد بررسی قرار گرفت. در نهایت حذف ماده رنگزای کاتیونی متیلن آبی و اثر pH بر روی سرعت حذف بررسی شد. با توجه به نتایج حاصل شده در محیط‌‌های اسیدی، زمان تماس 60 دقیقه و مقدار 0.1گرم از نانو کامپوزیت چارچوب آلی-فلزی مغناطیسی سنتز شده، بیشترین ظرفیت جذب ماده رنگزای کاتیونی متیلن آبی مشاهده شد. داده‌‌های تجربی با ایزوترم جذبی لانگمیور مطابقت خوبی داشتند. از طرفی مطالعات سینتیکی نشان داد که فرآیند جذب ماده رنگزای متیلن آبی در pHهای متفاوت، اغلب از مدل شبه مرتبه دوم پیروی می‌کند.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Synthesis and Application of Nanocomposite Containing Metal-Organic Framework and Magnetic Nanoparticles in Silica Matrix for Decolorization of Methylene Blue

نویسندگان [English]

  • M. Heydari
  • M. Gharagozlou
  • M. Ghahari
Department of Nanomaterials and Nanocoatings, Institute for Colour Science and Technology, P. O. Box: 16765-654, Tehran, Iran
چکیده [English]

In this study, a magnetic nanocomposite of metal-organic framework (NiFe2O4@SiO2@HKUST-1) with the weight ratio of nickel ferrite to silica matrix (10:90) was synthesized and characterized via the in-situ self-assemble method. Phase formation, type of formed bonds, morphology, crystal size, magnetic property and special surface area size werre characterized and investigated by X-Ray diffraction analysis (XRD), scanning electron microscopy (SEM) analysis, vibrating-sample magnetometer analysis (VSM) and Brunauer–Emmett–Teller analysis (BET). Finally, the removal of methylene blue cationic dye and the effect of pH on the removal rate were investigated. According to the obtained results in acidic environments, contact time of 60 minutes and 0.1 g of the synthesized magnetic nanocomposite of metal-organic framework, the highest adsorption capacity of the methylene blue cationic dye was observed. Experimental data were well-fitted with the Longmuir absorption isotherm. The kinetic studies showed that the process of adsorption of methylene blue dye at different pHs, was best described by a pseudo-second-order model.

کلیدواژه‌ها [English]

  • Magnetic nanocomposite
  • Metal-organic framework
  • Nanoparticles
  • Decolorization
  • Methylene blue
  • Adsorption

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