کاربرد کربن متخلخل در حذف رنگزای دیسپرس قرمز 167: بررسی سینتیکی و ترمودینامیکی فرایند جذب

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه آموزشی صنایع کاربردی، دانشگاه ملی مهارت، تهران، ایران، صندوق‌پستی: 1435763811

2 گروه آموزشی هنر، دانشگاه ملی مهارت، تهران، ایران، صندوق‌پستی: 1435763811

10.30509/jcst.2025.167594.1264

چکیده

در این تحقیق، از پوست گردو به‌عنوان ماده اولیه برای سنتز کربن فعال به روش شیمیایی با استفاده از فسفریک اسید استفاده شده است. هدف اصلی، بررسی توانایی این جاذب طبیعی در حذف رنگزای دیسپرس قرمز 167 از پساب‌های نساجی است. خصوصیات فیزیکی و شیمیایی جاذب با استفاده از آزمون‌های BET، SEM و عنصری بررسی شدند. تأثیر عوامل مختلفی مانند pH، زمان تماس، غلظت اولیه رنگزا و دما بر روی فرایند جذب مطالعه شد. ایزوترم‌های جذب، به همراه مدل‌های سینتیکی شبه مرتبه اول و دوم، برای مدل‌سازی داده‌های تجربی استفاده گردید. نتایج نشان دادند که جاذب سنتز شده دارای سطح ویژه بالا و ساختار متخلخل مؤثر در حذف رنگزا است و مدل شبه مرتبه دوم، بهترین برازش را با داده‌ها داشته است. مطالعات ترمودینامیکی نشان داد که فرایند جذب گرماگیر و به صورت خودبه‌خودی است. گرمای ایزوستریک جذب در پوشش نسبتاً پایین از ماده جاذب، برای نمونه سنتز شده برابر با 4/54 کیلوژول بر مول گزارش شد، که نشان‌دهنده ویژگی‌های فیزیکی-شیمیایی و ناهمگنی سطح کربن فعال سنتز شده است. 

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Application of Porous Carbon in the Removal of Disperse Red 167 dye: Kinetic and Thermodynamic Study of the Adsorption Process

نویسندگان [English]

  • Soodabeh Khalili 1
  • Nasim Hasani 2
  • Zoya Salahshoor 2
1 Department of Applied Industries engineering, Technical and Vocational University (TVU), P.O. Box: 1435763811, Tehran, Iran
2 Department of Arts, Technical and Vocational University (TVU), P.O. Box: 1435763811, Tehran, Iran
چکیده [English]

In this research, walnut shell was utilized as a raw material for the production of activated carbon through chemical synthesis using phosphoric acid. The main objective was to explore the efficacy of this natural adsorbent in the extraction of Disperse Red 167 (DR167) dye from textile wastewater. The physical and chemical properties of the adsorbent were examined using BET, SEM, and elemental analysis methods. Several factors, including pH, contact duration, initial dye concentration, and temperature, were analyzed for their effect on the adsorption process. Both adsorption isotherms and pseudo-first-order as well as pseudo-second-order kinetic models were employed to interpret the experimental data. The findings demonstrated that the produced adsorbent has a high specific surface area and a porous configuration, making it effective in dye removal. The pseudo-second-order kinetic model yielded the best correlation with the data. Thermodynamic investigations indicated that the adsorption process is endothermic and occurs spontaneously. The isosteric heat of adsorption at lower levels of coverage for the synthesized sample was measured at 54.4 kJ/mol, reflecting the physicochemical characteristics and surface variability of the activated carbon.

کلیدواژه‌ها [English]

  • Adsorption
  • Activated Carbon
  • Disperse Red 167
  • Walnut Shell

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