مطالعه اثر نیمه‌هادی و الکترود مقابل در بازده سلول‌های خورشیدی حساس شده به مواد رنگزا

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه پژوهشی مواد رنگزای آلی، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-167654

2 گروه پژوهشی نانوفناوری رنگ، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-167654

3 دانشکده فیزیک، دانشگاه صنعتی شاهرود، شاهرود، ایران، صندوق‌پستی: 316-36155.

10.30509/jcst.2024.167373.1238

چکیده

سلول‌های خورشیدی حساس‌شده به مواد رنگزا، یک فناوری کارآمد در تولید انرژی تجدیدپذیر بوده که برای تبدیل نور خورشید به انرژی الکتریکی معرفی شده­اند. برای تسهیل تجاری‌سازی این فناوری، جایگزینی بخش­های گران قیمت و کاهش پدیده بازترکیب، می‌تواند موثر باشد. برای این منظور اثر دو بخش نیمه‌هادی و الکترود مقابل
در تهیه سلول­های خورشیدی حساس شده به مواد رنگزا مورد بررسی قرار گرفت. نیمه هادی­ها در تهیه فوتوآند مورد استفاده قرار گرفته و الکترون تولید شده در اثر تهییج ماده رنگزا را دریافت می­کنند. در این پژوهش دو نیمه هادی اکسید روی و دی­اکسید تیتانیم دوپ شده با سدیم انتخاب و عملکرد آن‌ها با دی­اکسید تیتانیم مقایسه شد. دو ماده رنگزای آلی- معدنی دارای دو گروه الکترون‌ گیرنده مختلف به عنوان حساس‌کننده تهیه گردید. بیشترین بازده در حضور ماده رنگزای دارای گروه سیانوآکریلیک اسید و دی­اکسید تیتانیم دوپ شده با سدیم و در حدود 6.27 درصد به دست آمد. پلاتین به عنوان الکترود مقابل، بخش گران قیمت سلول‌های خورشیدی حساس شده به مواد رنگزا است. اکسید گرافن، هیبرید و کامپوزیت آن با دی‌سولفید مولیبدن برای جایگزینی پلاتین انتخاب گردید. اکسید گرافن دارای خواص الکتروکاتالیستی ضعیفی بوده که با استفاده از دی­سولفید مولیبدن این محدودیت برطرف می­گردد. بیشترین بازده در حضور ماده رنگزای دارای گروه سیانوآکریلیک اسید، کامپوزیت MoS2/GO و دی‌اکسید تیتانیم دوپ شده با سدیم در حدود 6.03 درصد به دست آمد. نتایج نشان داد که می‌توان از کامپوزیت MoS2/GO به جای پلاتین در ساختار سلول‌های خورشیدی حساس به مواد رنگزا استفاده کرد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Investigation of the Effect of Semiconductor and Counter Electrode on the Efficiency of Dye-Sensitized Solar Cells

نویسندگان [English]

  • Mozhgan Hosseinnezhas 1
  • Kamaladin Gharanjig 1
  • Mehdi Ghahari 2
  • Mohsen Fathi 3
1 Department of Organic Colorants, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
2 Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
3 Department of Physics, Shahrood University of Technology, P.O. Box: 36155-316, Shahrood, Iran
چکیده [English]

Dye-sensitized solar cells are a good option for producing renewable energy based on converting sunlight into electrical energy. To facilitate the commercialization of this technology, it can be effective to replace expensive parts and reduce the recombination phenomenon. For this purpose, two parts of the semiconductor and the counter electrode were investigated. Semiconductors are used in the photoanode preparation and receive the electron produced by the dye excitation. In this research, two semiconductors, ZnO and Na-doped TiO2, are selected, and their performance is compared with that of titanium dioxide. Two organometallic dyes with two different electron acceptor groups were prepared as sensitizers. The highest yield was obtained in the presence of organic dye containing cyanoacrylic acid and Na-doped TiO2, equal to 6.27 %. Platinum as the counter electrode is an expensive part of dye-sensitized solar cells. Graphene oxide, its hybrid, and its composite with MoS2 were investigated to replace platinum. Graphene oxide has weak electrocatalytic properties, which can be solved by using MoS2. The highest yield was obtained in organic dye containing cyanoacrylic acid, MoS2/GO composite, and Na-doped TiO2, equivalent to 6.03 %. The results illustrated that MoS2/GO can be used instead of platinum.

کلیدواژه‌ها [English]

  • Dye
  • sensitized solar cells ZnO Na
  • doped TiO2 MoS2/GO composite MoS2

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