حذف مواد رنگزای اسپرک موجود در پساب رنگرزی توسط جاذب چارچوب آلی فلزی

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه پژوهشی مواد رنگزای آلی، پژوهشکده مواد رنگزا، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-16765

2 گروه تحقیقات فناوری مواد و محیط زیست (MATTER)، دانشگاه بریتیش کلمبیای شمالی، پرنس جرج، بریتیش کلمبیا، کانادا، V2N4Z9

3 خدمات آزمایشگاهی تجربه‌ای شمالی بریتیش کلمبیا (هاب نوآوری راهکارهای زیست محیطی و اقلیمی در شمال بریتیش کلمبیا)، دانشگاه بریتیش کلمبیای شمالی، پرنس جورج، بریتیش کلمبیا، کانادا، V2N4Z9

4 گروه علوم محیط زیست، دانشگاه محیط زیست، دانشگاه بریتیش کلمبیای شمالی، پرنس جورج، بریتیش کلمبیا، کانادا، V2N4Z9

5 گروه پژوهشی رنگدانه های معدنی و لعاب، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-16765

6 گروه پژوهشی محیط‌زیست، پژوهشکده مواد رنگزا، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-16765

چکیده

مواد رنگزای موجود در اسپرک کاربرد زیادی در رنگرزی الیاف نساجی به ویژه فرش دستباف دارد. در رنگرزی الیاف سلولزی و پروتئینی مقدار قابل‌توجهی از این مواد رنگزا در پساب رنگرزی باقی‌می­ماند که عامل ایجاد آلودگی زیست‌محیطی می‌شود. در این پژوهش، سنتز و مشخصه‌یابی یک چارچوب آلی- فلزی حاوی گروه آمینو به منظور حذف مواد رنگزای موجود در پساب رنگرزی مورد بررسی قرار گرفته است. شرایط حذف رنگ به روش تک پارامتری بهینه‌سازی شده و اثر عوامل موثر مانند غلظت اولیه ماده رنگزا، مقدار جاذب و pH بررسی شده است. نتایج نشان می­دهد که چارچوب آلی فلزی سنتزشده قادر است در pH 5، زمان ۱۲۰ دقیقه، دمای محیط، مقدار جاذب ۰.۰۷ گرم بیشترین مقدار حذف رنگ را در محلولی با غلظت اولیه ۲۴۰ میلی‌گرم در لیتر انجام دهد. همچنین داده­های سینتیکی و ایزوترم جذب نشان می­دهند که سرعت حذف رنگ از رابطه نفوذ درون ذره­ای و ایزوترم فروندلیچ پیروی می‌کند. فرایند جذب مواد رنگزا توسط جاذب گرمازا و فیزیکی است.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Removal of Reseda Luteola Dyes in Dyeing Wastewater by Metal-organic Framework Adsorbent

نویسندگان [English]

  • Kamaladin Gharanjig 1
  • Hossein Kazemian 2 3 4
  • Mozhgan Hosseinnezhad 1
  • Ebrahim Ghasemi 5
  • Seyed Masoud Etezad 6
  • Siavash Goudarzi 1
  • Hooman imani 1
  • Hamid Gharanjig 1
1 Department of Organic Colorants, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
2 Materials Technology and Environmental Research (MATTER) lab, V2N4Z9, University of Northern British Columbia, Prince George, BC, Canada
3 Northern Analytical Lab Services (Northern BC's Environment and Climate Solutions Innovation Hub), V2N4Z9, University of Northern British Columbia, Prince George, BC, Canada
4 Environmental Sciences Program, Faculty of Environment, University of Northern British Columbia, Prince George, British Columbia, V2N4Z9
5 Department of Inorganic Glaze and Pigments, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
6 Department of Environmental Research, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran
چکیده [English]

The available dyes in the Reseda luteola are widely used in dyeing textile fibers, especially hand-made carpets. In the dyeing of cellulose and protein fibers, a significant amount of these dyes remain in the dyeing effluent, which causes environmental pollution. In this research, the synthesis and characterization of a metal-organic framework (MOF) containing an amino group has been investigated in order to remove the dyes present in the dyeing effluent. Dye removal conditions have been optimized by the single-parameter method, and the effect of effective factors such as the initial concentration of the dye, amount of adsorbent, and pH have been investigated. The results show that the synthesized MOF can remove the highest amount of dye in a solution with an initial concentration of 240 mg/l at pH 5, time 120 minutes, ambient temperature, and amount of adsorbent 0.07 g. Also, the kinetic data and adsorption isotherm show that the rate of dye removal follows intraparticle diffusion and Freundlich isotherm. The adsorption process is exothermic and physical adsorption process.

کلیدواژه‌ها [English]

  • Metal
  • organic framework Reseda luteola Dyeing Wastewater treatment Luteolin

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