حذف موثر اسید بلو 113 و اسید اورانژ 10 از پساب‌های صنعتی با استفاده از کامپوزیت مغناطیسی تهیه شده از پوست سخت میوه بنه بومی

نوع مقاله : مقاله پژوهشی

نویسندگان

گروه شیمی، دانشکده علوم پایه، دانشگاه آزاد اسلامی واحد سنندج، سنندج، ایران، صندوق پستی: 6616935391

چکیده

در این مطالعه یک کامپوزیت مغناطیسی کربن فعال (Activated carbon (AC)) با استفاده از روش ترموشیمیایی و هم‌رسوبی ذرات آهن تهیه گردید(AC/Fe3O4) . از پوست سخت میوه بنه بومی منطقه اورامان استان کردستان به عنوان ماده خام استفاده شد. خصوصیات ساختمانی جاذب تهیه شده با استفاده از آنالیزهای SEM، FT-IR، EDAX، BET و VSM مورد بررسی قرار گرفت. تصاویر SEM به وضوح شکل گیری یک جاذب متخلخل با تخلخل در گستره میکرو و مزو حفرات را نشان داد. نتایج آنالیزهای FT-IR و EDAX حضور آهن در ساختمان جاذب را اثبات نمود. با استفاده از تخلخل‌سنجی BET، سطح ویژه جاذب تولید شده قبل و بعد از ترسیب ذرات آهن به ترتیب 229.6 و 179.37 متر مربع بر گرم تعیین گردید. در شرایط بهینه میزان حذف رنگ‌های مورد مطالعه از محلول‌های مدل 91.2 و 98.6 درصد به ترتیب برای اسید بلو 113 و اسید اورانژ 10 حاصل شد. داده‌های سینیتیکی پیروی فرایند‌ حذف را از مدل شبه درجه دوم نشان داد. همچنین مدل فروندلیچ بهترین مدل برای توصیف فرایند‌ جذب سطحی بود.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Effective Removal of Acid Blue 113 and Acid Orange 10 from Industrial Wastewater Using a Magnetic Composite Prepared from the Hard Shell of the Native Bane Fruit

نویسندگان [English]

  • Bahram Ebrahimi
  • Sirwan Mohammadiazar
Department of Chemistry, Faculty of Sciences, Islamic Azad University, Sanandaj Branch, PO Box 6616935391, Sanandaj, Iran,
چکیده [English]

This study used thermochemical and Fe particle co-precipitation methods to prepare a magnetic-activated carbon composite. The hard nutshell of Baneh from the Oraman region of Kurdistan province was used as raw material. The structural properties of the prepared adsorbent were investigated using SEM, FT-IR, EDAX, BET, and VSM analysis methods. The SEM images clearly showed the formation of a porous adsorbent with porosity in the range of micro- and mesopores. The results of the FT-IR and EDAX analyses proved the presence of Fe in the absorbent structure. The specific surface area of the adsorbent before and after the deposition of iron particles was determined to be 229.6 and 179.37 m2/g, respectively. Under the optimized conditions, the removal amount of the investigated dyes from the model solutions was 91.2 and 98.6 % for acid blue 113 and acid orange 10, respectively. The kinetic study revealed that the pseudo-second-order model best fits the obtained adsorption data. In addition, the Freundlich model was the best model to describe the adsorption process.

کلیدواژه‌ها [English]

  • Baneh nut
  • Acid blue 113
  • Acid orange 10
  • Magnetic absorbent
  • Activated carbon
  • Magnetic composite

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