بررسی حذف هم‌زمان رنگزاهای متیلن آبی و بلور بنفش از محلول‌های آبی توسط جاذب مغناطیسی بر پایه کلینوپتیلولیت/آلژینات

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشکده مهندسی شیمی و نفت، دانشگاه تبریز، تبریز، ایران، صندوق پستی: 16471-51666

چکیده

حذف هم‌زمان رنگزاهای متیلن آبی و بلور بنفش با استفاده از جاذب­های نانوکامپوزیت کلینوپتیلولیت/Fe3O4 (Clin/Fe3O4­) و نانوکامپوزیت دانه­ای آلژینات/کلینوپتیلولیت/Fe3O4 (Alg/Clin/Fe3O4) مورد بررسی قرار گرفت. تاثیر عوامل محیطی موثر در فرآیند جذب شامل pH، مقدار جاذب، دما، زمان تماس و غلظت رنگ بررسی شد. نتایج نشان داد که بیشترین میزان جذب رنگزاها با استفاده از هر دو جاذب در شرایط 8=pH، دوز جاذب g/l 2، زمان تماس 60 دقیقه، دما 25 درجه سانتی‌گراد و غلظت رنگ ppm 10 به دست آمد. تحت شرایط بهینه، درصد جذب رنگزای متیلن آبی 80.36 و 74.51 درصد و درصد جذب رنگزای بلور بنفش 7.83 و 70.19 درصد به ترتیب با استفاده از جاذب­های Clin/Fe3O4­ و Alg/Clin/Fe3O4  به دست آمد. بررسی مدل­های ایزوترم نشان داد که فرآیند جذب هر دو ماده رنگزا، عمدتا به صورت فیزیکی و مطلوب می­باشد. داده­های تجربی مربوط به جذب رنگزاها با استفاده از هر دو جاذب با مدل ایزوترم لانگمویر و مدل سینتیکی شبه درجه دوم بیشترین تطابق را داشت. بررسی ترمودینامیکی نشان داد که فرآیند جذب گرمازا و خود به خودی بوده است.

کلیدواژه‌ها

عنوان مقاله [English]

Simultaneous Removal of Methylene Blue and Crystal Violet Dyes from Aqueous Solutions Using Magnetic Granular Adsorbent Based on Clinoptilolite/Alginate

نویسندگان [English]

  • Maryam Noori
  • Maryam Tahmasebpoor
Faculty of Chemical and Petroleum Engineering, University of Tabriz, P.O. Box: 51666-16471, Tabriz, Iran
چکیده [English]

Simultaneous removal of methylene blue and crystal violet was investigated. Adsorbents made of clinoptilolite/Fe3O4 (Clin/Fe3O4) nanocomposites and alginate/clinoptilolite/Fe3O4 (Alg/Clin/Fe3O4) nanocomposite beads were used. The effects of effective environmental parameters such as pH, adsorbent amount, temperature, contact time, and dye concentration were examined in the adsorption process. The results showed that the highest amount of dye adsorption using both adsorbents was obtained under pH = 8, adsorbent dose of 2 g/l, contact time of 60 minutes, temperature of 25 ºC, and dye concentration of 10 ppm. Under optimal conditions, the adsorption percentage of methylene blue dye was obtained as 80.36 and 74.51 %, and the adsorption percentage of crystal violet dye was obtained as 75.83 and 70.19 %, using Clin/Fe3O4 and Alg/Clin/Fe3O4 adsorbents, respectively. Investigating isothermal models showed that both dyes' adsorption process was mainly physical and desirable. Experimental data on dye adsorption using both adsorbents was most consistent with the Langmuir isotherm and the pseudo-second-order kinetic models. The thermodynamic study showed that the adsorption process was exothermic and spontaneous.

کلیدواژه‌ها [English]

  • Simultaneous dyes removal
  • Crystal violet
  • Methylene blue
  • Clinoptilolite
  • Magnetic adsorbent

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علوم و فناوری رنگ
دوره 17، شماره 1 - شماره پیاپی 63
اردیبهشت 1402
صفحه 33-50

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