سنتز مواد رنگزای آزو برپایه نفتول‌ها، زانتن‌ها و هیدروکسی کومارین‌ها با استفاده از کاتالیزور سلولزسولفونیک اسید

نوع مقاله : مقاله پژوهشی

نویسنده

گروه شیمی، دانشگاه پیام نور،تهران، ایران

چکیده

در این تحقیق، سلولزسولفونیک اسید به عنوان یک کاتالیزور جدید برای سنتز مواد رنگزای آزو برپایه نفتول ها، زانتن‌ها و هیدروکسی کومارین‌ها مورد استفاده قرار گرفت. همچنین کاتالیزور سلولزسولفونیک اسید قابل بازیافت بوده و در پنج مرحله مورد استفاده قرار گرفت. ساختار ترکیبات سنتز شده از طریق مقایسه خواص فیزیکی آنها با مقادیر گزارش شده قبل و به کمک داده‌های طیف‌سنجی زیر قرمز و 1HNMR تعیین گردید. نتیجه‌های به دست آمده نشان دادند که این واکنش‌های سنتزی بسیار ساده بوده و با بازده‌های خوب، مشتقات مواد رنگزای آزو را تولید می‌نمایند. شرایط ملایم، سرعت بالا و زمان کوتاه واکنش، سادگی روند جداسازی محصولات، بازده و خلوص بالای مشتقات سنتز شده از مزایای روش ارائه شده می‌باشد.

کلیدواژه‌ها

عنوان مقاله [English]

Synthesis of Azo Dyes Based on Naphthols, Xanthines, and Hydroxy Coumarins in the Presence of Cellulose Sulfonic Acid

نویسنده [English]

  • B. Baghernejad
Payme Noor UniversityDepartment of Chemistry, Payame Noor University, Tehran, Iran
چکیده [English]

This study used cellulosulfonic acid as a new catalyst for synthesizing azo dyes based on naphthol, xanthene, and hydroxycoumarin. Also, cellulosulfonic acid catalyst was recyclable and was used in five steps. The structure of the synthesized compounds was determined by comparing their physical properties with previously reported values using IR and HNMR spectroscopy data. The results showed that these synthetic reactions are elementary and produce azo dyes with good efficiencies. The advantages of the proposed method are the avoidance of environmentally harmful solvents, mild conditions, high speed and short reaction time, simplicity of working up process, high efficiency, and purity of synthesized derivatives.

کلیدواژه‌ها [English]

  • Synthesis
  • Azo
  • Cellulose sulfonic acid
  • Naphthol
  • Xanthen
  • Coumarin

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