نویسندگان
1 دانشکده مهندسی پلیمر و رنگ، دانشگاه صنعتی امیرکبیر
2 دانشکده مهندسی پلیمر و رنگ، دانشگاه صنعتی امیرکبیر
3 پژوهشکده رنگ و پلیمر، دانشگاه صنعتی امیرکبیر
چکیده
کلیدواژهها
عنوان مقاله [English]
نویسندگان [English]
In this research, a nanoceramic hexafluorozirconic acid based conversion coating free of phosphate salts was investigated. The effect of practical parameters such as solution pH, temperature and dipping time on coating morphology and anti-corrosion resistance of coating was evaluated. Anti-corrosion resistance of so-called nanoceramic conversion coating on cold rolled steel (CRS) substrates in different solution pH, temperatures and immersion’s time, utilizing DC Polarization was studied. The conversion coating which was formed at dipping temperature of 20 °C, pH=5 and immersion’s time of 60 seconds had the best anti-corrosion resistance. The morphology of the conversion coating surface formed at different pH was investigated using Atomic Force Microscopy (AFM). Images obtained from the microscope indicate that the conversion coating which formed in pH=5 was more consistent and had finer aggregates in comparison with pH=4.25 coating. Field Emission Scanning Electron Microscopy (FE-SEM) of conversion coating formed in 20 and 40 °C indicated that surface of conversion coating with higher temperature had micro cracks and was not uniform , also nodules on the scale of tens of nm (40–60 nm) in size, was observed on the surface.
کلیدواژهها [English]