The effect of aminated graphene oxide nanocomposite based on benzidine-zinc oxide on the corrosion resistance of cathode electrocoatings

Document Type : Original Article

Authors

1 Faculty of chemistry, Islamic Azad University, North Tehran Branch

2 member of institute for color science and technology

3 PhD student of chemical faculty,Islamic Azad University, North Tehran Branch

4 faculty member , chemical faculty, Islamic Azad University , North Tehran Branch

Abstract

In this study, graphene oxide is functionalized with benzidine and zinc oxide nanoparticles to improve adhesion and corrosion resistance properties. Nanoparticles were dispersed in an epoxy-based coating and applied as a coating on steel panels. The corrosion resistance of nano composite coatings was evaluated by salt spray test during 45 days of exposure. The results showed that the anti-corrosion performance of the coating containing 0.01% graphene oxide containing amine-zinc oxide with a penetration depth of 1.2 mm from scratch showed the highest corrosion resistance. The results of the salt spray and EIS tests show that with the increase of nanoparticles up to 0.01%, the anti-corrosion properties increased.

Keywords

Main Subjects

References

  1.  Montemor M. Functional and smart coatings for corrosion protection: A review of recent advances. Surf Coat Technol. 2014;258: 17-37. https://doi.org/10.1016/j.surfcoat.2014.06.031
  2.  Munger G. Corrosion prevention by protective coatings. 1985.
  3.  Rashvand M. Ranjbar Z. Study of the effect of nano zinc oxide and nano titania particles as uv stabilizer in the waterborne polyurethane coatings in accelerated weathering conditions. J Color Sci Tech. 2013;7(1):69-74. dor:20.1001.1.17358779.1392.7.1.8.7 [In Persian].
  4.  Esfahani SL, Ranjbar Z, Rastegar S. An electrochemical and mechanical approach to the corrosion resistance of cathodic electrocoatings under combined cyclic and DC polarization conditions. Prog Org Coat. 2014;77(8):126470.https://doi.org/10.1016/j.porgcoat.2014.03.028.
  5.  Lajevardi Esfahani S, Ranjbar Z, Rastegar S. Investigation of Protective Behavior of Different Cathodic Electrocoatings Using Different Anti-Corrosive Tests (Modified AC/DC/AC Test, EIS and Salt Spray). J Color Sci Tech. 2014;8(2):117-28.dor:20.1001.1.17358779.1393.8.2.4.2[in Persian]
  6.  Wan YJ, Tang LC, Gong LX, Yan D, Li YB, Wu LB. et al. Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties. Carbon. 2014;69:467-80.doi: https://doi.org/10.1016/j.carbon.2013.12.050.
  7.  Ma Y, Di H, Yu Z, Liang L, Lv L, Pan Y. et al. Fabrication of silicadecorated graphene oxide nanohybrids and the properties of composite epoxy coatings research. Appl surf Sci. 2016;360:936-45.doi: https://doi.org/10.1016/j.apsusc.2015.11.088.
  8.   Ramezanzadeh B, Rasi E, Mahdavian M. Studying various mixtures of 3-Aminopropyltriethoxysilane (APS) and Tetraethylorthosilicate (TEOS) silanes on the corrosion resistance of mild steel and adhesion properties of epoxy coating. Int J adhes adhes. 2015; 63:166-76.doi: https://doi.org/10.1016/j.ijadhadh.2015.09.007.
  9. Rashvand M, Ranjbar Z. Cathodic electrodeposion of nano Titania along the epoxy based coating and evaluation of its anticorrosion properties. Prog Color, Colorants Coat. 2014;7(4):227-35.doi: 10.30509/pccc.2014.75836
  10. Ramezanzadeh B, Rostami M. The effect of cerium-based conversion treatment on the cathodic delamination and corrosion protection performance of carbon steel-fusion-bonded epoxy coating systems. Appl Surf Sci. 2017;392:1004-16.doi:https://doi.org/10.1016/j.apsusc.2016.09.140
  11. Luo X, Zhong J, Zhou Q, Du S, Yuan S, Liu Y. Cationic reduced graphene oxide as self-aligned nanofiller in the epoxy nanocomposite coating with excellent anticorrosive performance and its high antibacterial activity. ACS Appl Mater Interfaces. 2018;10:18400-415.doi: https://doi.org/10.1021/acsami.8b01982.
  12. Amrollahi S, Ramezanzadeh B, Yari H, Ramezanzadeh M, Mahdavian M. Synthesis of polyaniline-modified graphene oxide for obtaining a high performance epoxy  nanocomposite film with excellent UV blocking/anti-oxidant/anti-corrosion capabilities. Composites. Part B. 2019;173:106804.doi: https://doi.org/10.1016/j.compositesb.2019.05.015.
  13. Cheng H, Huang Y, Cheng Q, Shi G, Jiang L, Qu L. Self-healing graphene oxide based functional architectures triggered by moisture. Adv Funct Mater. 2017;27:1703096. doi: https://doi.org/10.1002/adfm.201703096.
  14. Parhizkar N, Shahrabi T, Ramezanzadeh B. A New Approach for Enhancement of the Corrosion Protection Properties and Interfacial Adhesion Bonds between the Epoxy Coating and Steel Substrate through Surface Treatment by Covalently Modified Amino Functionalized Graphene Oxide Film. Corrosion science. 2017;123:55-75.doi:https://doi.org/10.1016/j.corsci.2017.04.011.
  15. Bedair MA, Soliman SA, Bakr MF, Gad ES, Hassane Lgaz, Ill-Min. Chung, Mohamed Salama, Faleh Z. Alqahtany, Benzidine-based Schiff base compounds for employing as corrosion inhibitors for carbon steel in 1.0 M HCl aqueous media by chemical, electrochemical and computational methods, J. Mol. Liq. 2020;317.doi:https://doi.org/10.1016/j.molliq.2020.114015.
  16. Tedim J, Poznyak SK, Kuznetsova A, Raps D, Hack T, Zheludkevich ML, et al. Enhancement of active corrosion protection via combination of inhibitor-loaded nanocontainers. ACS Appl Mater Interfaces. 2010;2:1528-35.doi: https://doi.org/10.1021/am100174t.
  17. Yan D, Liu J, Zhang Z, Wang Y, Zhang M, Song D, et al. Dual-functional graphene oxide-based nanomaterial for enhancing the passive and active corrosion protection of epoxy coating. Composites Part B. 2021;222:109075.doi: https://doi.org/10.1016/j.compositesb.2021.109075.
  18. Farahin Ibrahim N, Rafizah Wan Abdullah W, Syazrinni Rooshde M, Sabri Mohd Ghazali M, Mohd Norsani Wan Nik W. Corrosion Inhibition Properties of Epoxy-Zinc Oxide Nanocomposite Coating on Stainless Steel 316L. Solid State Phenom. 2020;307:285-90.doi: https://doi.org/10.4028/www.scientific.net/SSP.
  19. Somoghi R, Purcar V, Alexandrescu E, Catalina Gifu I, Mihaela Ninciuleanu C, Mihai Cotrut C, et al. Synthesis of Zinc Oxide Nanomaterials via Sol-Gel Process with Anti-Corrosive Effect for Cu, Al and Zn Metallic Substrates. Coatings. 2021;11:444.doi: https://doi.org/10.3390/coatings11040444.
  20. Dad Chandio A, Hamza Saleem M, Raza Khan H, Naeem Hyder I, Ali M. Modified Zinc Oxide Nanoparticles for Corrosion Resistance Applications. J Chem Soc Pak. 2020;42: 705-12.
  21. Hedayati K. Fabrication and Optical Characterization of Zinc Oxide Nanoparticles Prepared via a Simple Sol-gel Method. J Nanostruct. 2015;5:395-401.doi: https://doi.org/10.7508/JNS.2015.04.010.
  22. Khorsand Zak A, Razali R, Abd Majid WH, Darroudi M. Synthesis and characterization of a narrow size distribution of zinc oxide nanoparticles. Int J Nanomed. 2011;6: 1399-1403. doi: 10.2147/IJN.S19693.
Journal of Color Science and Technology
Volume 17, Issue 2 - Serial Number 64
September 2023
Pages 159-167

Files

Share

How to cite

Statistics