Adsorption of Indigo Dye Using Magnetic Chitosan-Itaconic Acid Nano Fibers and Investigation of Kinetics and Absorption Isotherm Models

Document Type : Original Article

Authors

1 Oil and Chemical Engineering Department, Science and Research Branch, Islamic Azad University, Tehran, Iran

2 Chemical Engineering Department, Varamin-Pishva Branch, Islamic Azad University, Varamin, Iran

3 Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran

Abstract

Today, the treatment of industrial wastewater, including textile is in a high importance. Actually the use of nanomaterials in the removal of wastewater from sewage has attracted widespread attention in recent years. The color of the Indigo is one of these pollutants. In this study, optimum nano fiber chitosan-itaconic acid was prepared using experimental design and in the following adsorption of Indigo dye wastewater treatment and the study of its kinetics and its isotherm was investigated. X-ray diffraction (XRD), Field Emission Scanning Electron Microscopes (FESEM), Infrared Fourier Transform (FT-IR), Vibrational Sampler Magnetic Meter (VSM) and thermal gravimetric analysis (TGA) are also used to study synthesize nano-fibers. Also, the effect of the initial concentrations of pollutants for absorbance, contact time, temperature and pH were investigated.In this study, the optimal concentration of Indigo 100 ppm, optimal time of 45 minutes and optimal pH 3 was obtained. The mechanism absorption of chitosan-itaconic acid follows the pseudo first-order kinetics and Freundlich isotherm model. 

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Main Subjects

References

  1. A. Asfaram, M. R. Fathi, Removal of direct red 12b dye from aqueous solutions by wheat straw: isotherms, kinetics and thermodynamic studies. J. Color. Sci. Tech. 7(2013), 223-235.
  2. S. P. Moussavi, M. Mohammadian Fazli, Acid violet 17 dye decolorization by multi-walled carbon nanotubes from aqueous solution. J. Hum. Environ. Health Promot. 1(2016), 110-117.
  3. E. Forgacs, T. Cserhati, G. Oros, Removal of synthetic dyes from wastewaters: a review. Environ. Int. 30(2004), 953–71.
  4. G. Crini, Non-conventional low-cost adsorbents for dye removal: a review. Bioresour. Technol. 97(2006), 1061–85.
  5. A. M. Mashhadzadeh, A. M. Vahedi, M. Ardjmand, M. G. Ahangari, Investigation of heavy metal atoms adsorption onto graphene and graphdiyne surface: a density functional theory study. Superlattic Microstruct. 100(2016), 1094–1102.
  6. L. Zhou, C. Gao, W. Xu,Magnetic dendritic materials for highly efficient adsorption of dyes and drugs. Appl. Mater. Interfaces, 2(2010), 1483-1491.
  7. G. Gibbs, J. Tobin, E. Guibal, Influence of chitosan pre-protonation on reactive black 5 sorption isotherms and kinetics. Ind. Eng. Chem. Res. 43(2004), 1-11.
  8. N. K. Lazaridis, G. Z. Kyzas, A. Vassiliou, D. N. Bikiaris, Chitosan derivatives as biosorbents for basic dyes. Langmuir. 23(2007), 7634- 7643.
  9. R. Tang, Z. Yu, Y. Zhang, Biopolymer, Synthesis, characterization and properties of antibacterial dye based on chitosan. Cellulose. 23(2016), 1741-1749.
  10. A. Bée, L. Obeid, R. Mbolantenaina, M. Welschbillig, D. Talbot, Magnetic chitosan/clay beads: Amagsorbent for the removal of cationic dye fromwater. J. Magn. Mater. 421(2017), 59-64.
  11. P. Hu, J. Wang, R. Huang, Simultaneous removal of Cr (VI) and Amido black 10B (AB10B) fromaqueous solutions using quaternized chitosancoated bentonite. Int. J. Biol. Macromol. 92(2016), 694-701.
  12. Sh. Shahsavari, E. Vasheghani-Farahani, M. Ardjmand, FA. Dorkoosh, Design and characterization of acyclovir loaded nanoparticles for controlled delivery system. Curr. Nanosci. 10(2014), 521-531.
  13. S. k. Jesudoss, J. J. Vijaya, L. John Kennedy, P. I. Rajan, H. A. Al-Lohedan, Studies on the efficient dual performance of Mn1-xNixFe2O4 spinel nanoparticles in photodegradation and antibacterial activity. J. Photochem. Photobiol. B. 165(2016), 121-131.
  14. Y. Zheng, A. Wang, Superadsorbent with three-dimensional networks: From bulk hydrogel to granular hydrogel. Eur. Polym. J. 72(2015), 661-686.
  15. Y. Achour, A. Hafid, L. My Rachid, M. Khouili, DFT investigations and experimental studies for competitive and adsorptive removal of two cationic dyes onto an eco-friendly material from aqueous media. Int. J. Environ. Res. 12(2016), 789–802.
  16. K. Bing Tan, M. Vakili,Bahman Amini Horri, P. Eong Poh, A. Zuhairi Abdullah, B. Salamatinia, Adsorption of dyes by nanomaterials: recent developments and adsorption mechanisms. Sep. Purif. Technol. 150(2015) 229–242.
  17. S. Gu, J. Xieb, CM. Li, Hierarchically porous graphitic carbon nitride: large-scale facile synthesis and its application toward photocatalytic dye degradation. RSC Adv. 4(2014), 436-439.
  18. L. Lili, C. Xueling, W. Yuqing, L. Dawei, H. Dandan, Synthesis of organofunctionalized magnetic microspheres and application foranionic dye removal, J. Taiwan. Inst. Chem. E. 44 (2013) 67–73.
  19. J. Zhang, Q. Zhou, L. Ou, Kinetic, Isotherm, and Thermodynamic Studies of the Adsorption of Methyl Orange from Aqueous Solution by Chitosan/Alumina Composite. J. Chem. Eng. Data. 57(2012), 412-419.
  20. R. G. Saratale, G. D. Saratale, J. S. Chang, S. P. Govindwar, Bacterial decolorization and degradation of azo dyes: A review. J. Taiwan. Inst. Chem.  42(2011), 138–157.
  21. F. Bari, N. Begum, S.B. Jamaludin, K. Hussin,Extraction and separation of Cu (II), Ni (II) and Zn (II) by sol–gel silica immobilized with Cyanex 272. Hydrometallurgy. 96(2009), 140-147.
  22. Y. Bulut, H. Aydın, A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination. 194(2006), 259-267.
  23. Z. Zhou,Adsorption of food dyes from aqueous solution by glutaraldehyde cross-linked magnetic chitosan nanoparticles. J. Food Eng. 126(2014), 133-141.
  24. M. T. Yagub, TK. Sen, H. Ang, Equilibrium, kinetics, and thermodynamics of methylene blue adsorption by pine tree leaves. Water Air Soil Pollut. 223(2012), 5267-5282.
  25. Y. Zheng, A. Wang, Superadsorbent with three-dimensional networks: From bulk hydrogel to granular hydrogel. Eur. Polym. J. 72(2015), 661-686.
  26. RG. Saratale, R. Saratale, J. S. Chang, S. P. Govindwar, Bacterial decolorization and degradation of azo dyes: a review. J. Taiwan. Inst. Chem. E. 42(2011), 138-157.
  27. L. Fan, C. Luo, Z. Lv, F. Lu, H. Qiu, preparation of magnetic modified chitosan and adsorption of Zn2 from aqueous solution. Colloids Surf. B. 88(2011), 574-581.
  28. S. Sundaram, R. Jayaprakasam, M. Dhandapani, T. S. Senthil, V. N. Vijayakumar, Theoretical (DFT) and experimental studies on multiple hydrogen bonded liquid crystals comprising between aliphatic and aromatic acids. J Mol Liq. 243(2017), 14–21.
  29. H. salehi, M. Mirzaee, Experimental study of influencing factors and kinetic in catalitic removal of methylene blue with TiO2 nano power. Am. J. Environ. Eng. 2(2012), 1-7.
  30. A. Mohseni-Bandpei, B. Kakavandi, R. Rezaei kalantary, A. Azari, Development of a novel magnetite-chitosan composite for the removal of fluoride from drinking watrer: adsorption modeling and optimization. Rsc Advances. 89(2015), 73279-73289.
  31. M. Asgarzadeh, Sh. Shahsavari, A. Vaziri-Yazdi, E. Moniri, Design of magnetic chitosan nanoparticles for targeted cancer therapy using 5-fluorouracil in glycerol-moonoleate. J. Appl. Res.Chem. Polym. Eng. 2(2018), 45-56.
  32. Sh. Lehyani, R. Hassan, A. Alharbi, T. Alomayri, H. Alamri. Magnetic Hyperthermia using cobalt ferrite nanoparticles: the influence of particle size. Int. J. Adv. Technol. 8(2017), 567-579.
Journal of Color Science and Technology
Volume 14, Issue 2
July 2020
Pages 117-128

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