تجزیه کاتالیزوری نوری رنگزای متیل اورانژ با استفاده از نانومیله‌های روی اکسید/ الیاف پلی آکریلو نیتریل

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه شیمی‌فیزیک و نانو، دانشکده شیمی، دانشگاه الزهرا، تهران، ایران صندوق پستی: 93973-19938

2 گروه شیمی‌فیزیک و نانو، دانشکده شیمی، دانشگاه الزهرا، تهران، ایران، صندوق پستی: 93973-19938

چکیده

در این پژوهش نانومیله‌های روی اکسید (ZnO) با روش رسوب‌دهی حمام شیمیایی بر روی دو نوع از نانو الیاف الکتروریسی شده پلی آکریلو نیتریل(PAN)  به منظور تجزیه کاتالیزوری نوری رنگزای متیل اورانژ (MO) رشد داده شد. به منظور دستیابی به بالاترین سرعت تجزیه کاتالیزوری نوری ساختارهای مختلفی از ZnO با تغییر مشخصه‌های رشد نانومیله­ها از جمله زمان رشد، غلظت محلول رشد و زیر لایه رشد با استفاده از طراحی آزمایش‌ها به روش Design of Expert (DOE) مورد بررسی قرار گرفت. الگوی پرتو ایکس (XRD) ساختار بلوری ورﺗﺴﺎﯾﺖ و آنالیز طیف‌سنجی بازتابی نفوذی (DRS) شکاف انرژی eV 3.2 را برای ZnO نشان داد. همچنین نمونه بهینه‌سازی شده با زمان رشد 10 ساعت و غلظت 62.5 میلی‌مولار از محلول رشد روی نیترات و هگزا متیلن تتراآمین (HMTA)، ثابت سرعت تجزیه(k)  min-1 0.0038 را نشان داد.  انعطاف­پذیری، بازیابی سریع و راحت کاتالیزور نوری از پساب تصفیه­شده، همچنین سنتز آسان و ارزان نوید بخش کاربردهای عملیاتی نمونه‌های سنتز شده است.

کلیدواژه‌ها

عنوان مقاله [English]

Photocatalytic Degradation of Methyl Orange Dye Using Zinc Oxide Nanorods/polyacrylonitrile Fibers

نویسندگان [English]

  • Leyla Alizadeh Asl 1
  • Morasae Samadi 2
1 Department of Physical Chemistry and Nanochemistry, Faculty of Chemistry, Alzahra University, P.O. Box: 19938-93973, Tehran, Iran
2 Department of Physical Chemistry and Nanochemistry, Faculty of Chemistry, Alzahra University, P.O. Box: 19938-93973, Tehran, Iran
چکیده [English]

In this research, zinc oxide (ZnO) nanorods were grown by chemical bath deposition method on two types of electrospun polyacrylonitrile (PAN) nanofibers for photocatalytic decomposition of methyl orange dye. Various structures of ZnO were investigated to achieve the maximum rate of photocatalytic degradation by adjusting the growth variables of nanorods, including growth time, concentration of growth solution, and growth substrate, using the design of Expert (DOE) technique. The X-ray diffraction (XRD) pattern of the sample confirmed the wurtzite crystal structure, and diffuse reflectance spectroscopy (DRS) analysis showed an energy gap of 3.2 eV for ZnO. Also, the optimized sample with a growth time of 10 hours and a concentration of 62.5 mM of zinc nitrate and hexamethylenetetramine (HMTA) showed a decomposition rate constant (k) of 0.0038 min-1. Flexibility, quick and convenient recovery of photocatalyst from treated wastewater, and easy and cheap synthesis method promise the operational applications of the synthesized samples.

کلیدواژه‌ها [English]

  • Electrospinning
  • Photocatalyst
  • Nanocomposite
  • Semiconductor
  • Flexible membrane
  • Polyacrylonitrile

مراجع

  1. Ahmad HA, Ahmad S, Cui Q, Wang Z, Wei H, Chen X, et al. The environmental distribution and removal of emerging pollutants, highlighting the importance of using microbes as a potential degrader: A review. Science of The Total Environment. 2022;809:151926.
  2. Ahmed S, Mofijur M, Nuzhat S, Chowdhury AT, Rafa N, Uddin MA, et al. Recent developments in physical, biological, chemical, and hybrid treatment techniques for removing emerging contaminants from wastewater. Journal of hazardous materials. 2021;416:125912.
  3. Yang J, Shojaei S, Shojaei S. Removal of drug and dye from aqueous solutions by graphene oxide: Adsorption studies and chemometrics methods. NPJ Clean Water. 2022;5(1):5.
  4. Khodadadi T, Solgi  E, Mortazavi S, Nourmoradi H, Comparison of Advanced Oxidation Methods (AOPs) of Persulfate in Removal of Color in Municipal Wastewater, J. Color Sci. Tech. 2021;15(3):215-223. https://dorl.net/dor/ 20.1001.1. 17358779.1400.15.3.6.5 [In persian].
  5. Samadi M, Zirak M, Naseri A, Khorashadizade E, Moshfegh AZ. Recent progress on doped ZnO nanostructures for visible-light photocatalysis. Thin Solid Films. 2016;605:2-19.
  6. Samadi M, Zirak M, Naseri A, Kheirabadi M, Ebrahimi M, Moshfegh AZ. Design and tailoring of one-dimensional ZnO nanomaterials for photocatalytic degradation of organic dyes: a review. Research on Chemical Intermediates. 2019;45:2197-254.
  7. Lu M. Photocatalysis and water purification: from fundamentals to recent applications: John Wiley & Sons; 2013.
  8. Muñoz-Batista MJ, Muñoz AN, Luque R. Heterogeneous photocatalysis: recent advances: Springer; 2020.
  9. Naseri A, Samadi M, Moshfegh AZ. Visible-Light Active Photocatalysts in Pollutant Degradation/Conversion with Simultaneous Hydrogen Production.  UV‐Visible Photocatalysis for Clean Energy Production and Pollution Remediation2023. p. 9-26.
  10. Naseri A, Samadi M, Ebrahimi M, Kheirabadi M, Moshfegh AZ. Heterogeneous photocatalysis by organic materials: from fundamental to applications.  Current Developments in Photocatalysis and Photocatalytic Materials: Elsevier; 2020. p. 457-73.
  11. Djurišić A, Ng AMC, Chen X. ZnO nanostructures for optoelectronics: Material properties and device applications. Progress in quantum electronics. 2010;34(4):191-259.
  12. Schmidt-Mende L, MacManus-Driscoll JL. ZnO–nanostructures, defects, and devices. Materials today. 2007;10(5):40-8.
  13. Raha S, Ahmaruzzaman M. ZnO nanostructured materials and their potential applications: progress, challenges and perspectives. Nanoscale Advances. 2022;4(8):1868-925.
  14. Hezam A, Drmosh Q, Ponnamma D, Bajiri MA, Qamar M, Namratha K, et al. Strategies to enhance ZnO photocatalyst's performance for water treatment: a comprehensive review. The Chemical Record. 2022;22(7):e202100299.
  15. Chang JS, Strunk J, Chong MN, Poh PE, Ocon JD. Multi-dimensional zinc oxide (ZnO) nanoarchitectures as efficient photocatalysts: What is the fundamental factor that determines photoactivity in ZnO? Journal of hazardous materials. 2020;381:120958.
  16. Das A, Nair RG. Effect of aspect ratio on photocatalytic performance of hexagonal ZnO nanorods. Journal of Alloys and Compounds. 2020;817:153277.
  17. Leelavathi A, Madras G, Ravishankar N. Origin of enhanced photocatalytic activity and photoconduction in high aspect ratio ZnO nanorods. Physical Chemistry Chemical Physics. 2013;15(26):10795-802.
  18. Abdullah F, Bakar NA, Bakar MA. Current advancements on the fabrication, modification, and industrial application of zinc oxide as photocatalyst in the removal of organic and inorganic contaminants in aquatic systems. Journal of hazardous materials. 2022;424:127416.
  19. Xue Y, Kamali M, Zhang X, Askari N, De Preter C, Appels L, et al. Immobilization of photocatalytic materials for (waste) water treatment using 3D printing technology–advances and challenges. Environmental Pollution. 2022:120549.
  20. Kazemi P, Salem Sh. Dye Degradation by Anatase Coated on Meta-kaolin Support, J. Color Sci. Tech. 2019;12(4):281-292. https://dorl.net/dor/20.1001.1.17358779.1397.12.4.5.5 [In persian].
  21. Ali HM, Roghabadi FA, Ahmadi V. Solid-supported photocatalysts for wastewater treatment: Supports contribution in the photocatalysis process. Solar Energy. 2023;255:99-125.
  22. Le AT, Duy HLT, Cheong K-Y, Pung S-Y. Immobilization of zinc oxide-based photocatalysts for organic pollutant degradation: A review. Journal of Environmental Chemical Engineering. 2022:108505.
  23. Joseph A, Vijayanandan A. Review on support materials used for immobilization of nano-photocatalysts for water treatment applications. Inorganica Chimica Acta. 2022:121284.
  24. Samadi M, Moshfegh AZ. Recent Developments of Electrospinning-Based Photocatalysts in Degradation of Organic Pollutants: Principles and Strategies. ACS omega. 2022;7(50):45867-81.
  25. Samadi M, Shivaee HA, Pourjavadi A, Moshfegh AZ. Synergism of oxygen vacancy and carbonaceous species on enhanced photocatalytic activity of electrospun ZnO-carbon nanofibers: Charge carrier scavengers mechanism. Applied Catalysis A: General. 2013;466:153-60.
  26. Lausecker C, Salem B, Baillin X, Consonni V. Effects of zinc nitrate and HMTA on the formation mechanisms of ZnO nanowires on Au seed layers. Crystal Growth & Design. 2023;23(4):2941-50.
  27. Strano V, Urso RG, Scuderi M, Iwu KO, Simone F, Ciliberto E, Spinella C, Mirabella S. Double role of HMTA in ZnO nanorods grown by chemical bath deposition. The Journal of Physical Chemistry C. 2014;118(48):28189-95.
  28. Lee KS, Park CW, Kim JD. Electrochemical properties and characterization of various ZnO structures using a precipitation method. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2017;512:87-92.
  29. Samadi M, Shivaee HA, Zanetti M, Pourjavadi A, Moshfegh A. Visible light photocatalytic activity of novel MWCNT-doped ZnO electrospun nanofibers. Journal of Molecular Catalysis A: Chemical. 2012;359:42-8.
  30. Swamy CK, Hezam A, Ramesh AM, Ramakrishnegowda DH, Purushothama DK, Krishnegowda J, et al. Microwave hydrothermal synthesis of copper induced ZnO/gC3N4 heterostructure with efficient photocatalytic degradation through S-scheme mechanism. Journal of Photochemistry and Photobiology A: Chemistry. 2021;418:113394.
  31. Nikam AV, Prasad BL, Kulkarni AA. Wet chemical synthesis of metal oxide nanoparticles: a review. CrystEngComm. 2018;20(35):5091-107.
  32. Tissera ND, Wijesena RN, Sandaruwan CS, de Silva RM, de Alwis A, de Silva KN. Photocatalytic activity of ZnO nanoparticle encapsulated poly (acrylonitrile) nanofibers. Materials Chemistry and Physics. 2018;204:195-206.

فایل ها

هم رسانی

ارجاع به این مقاله

آمار