بررسی اثر مواد سطح‌فعال غیریونی بر کارآیی فرآیند استخراج مواد رنگزای طبیعی با استفاده از روش فراصوت و خصوصیات رنگی نخ پشمی

نوع مقاله : مقاله پژوهشی

نویسندگان

1 پژوهشکده مواد رنگزا، گروه‌ مواد رنگزای آلی، پژوهشگاه رنگ، صندوق‌پستی: 654-16765

2 مرکز مطالعات و همکاری‌های علمی بین المللی وزارت علوم تحقیقات و فناوری

3 دانشکده مهندسی شیمی، دانشگاه آلتو فنلاند، صندوق‌پستی: اس‍پو ۰۲۱۵۰

4 دانشکده علوم پایه، دانشگاه تربیت تدبیر شهید رجایی، صندوق‌پستی :۱۶۳-۱۶۷۸۵

چکیده

فرآیند استخراج در جداسازی و خالص‌سازی اجزای موجود در گیاهان بسیار بااهمیت است. برای حصول ترکیب­های طبیعی باارزش، روش­های استخراج مختلفی مطرح شده است که هرکدام از آنها نسبت به روش سنتی استخراج، با توجه به مصرف حلال کمتر، زمان کوتاه‌تر و آلودگی کمتری ایجاد می­کند. در این پژوهش، تأثیر مواد سطح­فعال غیریونی با غلظت‌های مختلف در استخراج رنگزاهای طبیعی روناس، اسپرک و پوست­گردو به روش فراصوت مورد بررسی قرار گرفت. نتایج نشان داد که استفاده از مواد سطح­فعال میزان استخراج ترکیبات رنگی موجود در رنگزاهای ذکر شده را بهبود داد. ازآنجاکه ترکیبات رنگی موجود در هر یک از گیاهان رنگی مورد استفاده متفاوت است، بازده استخراج در حضور هرکدام از سطح فعال­ها، متفاوت است. بطوریکه در رنگزای اسپرک در حضور سطح فعال Keol، فرآیند استخراج به مقدار 60 درصد فرآیند استخراج بهبود یافته است. همچنین، قدرت رنگی نخ های پشمی رنگ شده در حضور سطح­فعال­ها نسبت به نمونه رنگ شده شاهد (بدون سطح فعال) بین ۳۰ تا ۴۴ درصد افزایش یافته­است. نتایج این تحقیق بخوبی نشان می­دهد که می­توان از مواد فعال سطحی غیریونی برای بهبود فرآیند استخراج رنگزاهای طبیعی و میزان رنگزای جذب شده به صورت یکنواخت بر روی نخ‌های پشمی استفاده کرد.

کلیدواژه‌ها

عنوان مقاله [English]

Study on the Effect of Different Non-ionic Surfactants on the Efficiency of the Extraction Process of Natural Dyes Using the Ultrasonic Method and Dyeing Characteristics of Wool Yarn

نویسندگان [English]

  • M. Sadeghi-Kiakhani 1 2
  • Ali R. Tehrani-Bagha 3
  • R. Aladpoush 1
  • E. Hashemi 4
1 Institute for Color Science and Technology, Department of Organic Colorants, P.O. Box: 16765-654, Tehran-Iran|International Scientific Studies and Cooperation Center of the Ministry of Science, Research and Technology
2 Institute for Color Science and Technology, Department of Organic Colorants, P.O. Box: 16765-654, Tehran-Iran|International Scientific Studies and Cooperation Center of the Ministry of Science, Research and Technology
3 School of Chemical Engineering, Aalto University, Espoo 02150-Finalnd
4 Department of Chemistry, Faculty of Sciences, Shahid Rajaee teacher training university, P.O. Box: 16785-163, Tehran, Iran
چکیده [English]

The extraction process is very important in separating and purifying dye components from the natural plants. Various extraction methods have been used to obtain valuable natural compounds. Compared to the traditional extraction method, each has advantages, including less solvent consumption, shorter time, and less environmental pollution. This research studied the effect of non-ionic surfactants at various initial concentrations in extracting natural colorants from madder, weld, and walnut. The results showed that using surfactants improved the amount of extracted colored compounds in the extraction process. The efficiency of the extraction process in the presence of each surfactant is diverse due to the different color compounds in each colorant used. The extraction process of weld natural dye has been improved by 60 % in the presence of Keol surfactant. Also, the color strength of dyed wool yarns in the presence of surfactants has increased by 30-44 % compared to the control dyed sample (without surfactants). The results of this research clearly show that it is possible to use non-ionic surfactants to improve the extraction efficiency, color strength, and better leveling of the natural dyes on the wool yarn.

کلیدواژه‌ها [English]

  • Extraction
  • Natural dye
  • Surfactant
  • Ultrasound
  • Dyeing
  • Wool yarn

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