سنتز، مشخصه‌یابی و خواص جذبی نانوکامپوزیت‌های مغناطیسی (M: Mg, Mn, Ni) Polyaniline@MFe2O4

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه علوم پایه، دانشکده فنی مهندسی گلپایگان، دانشگاه صنعتی اصفهان، گلپایگان، ایران، صندوق پستی: 67498-87717

2 مرکز تحقیقات مواد اولیه دارویی، دانشگاه علوم پزشکی تهران، دانشگاه آزاد اسلامی، تهران، ایران، کد پستی: 1941933111

3 گروه شیمی دارویی، دانشکده شیمی دارویی، دانشگاه علوم پزشکی تهران، دانشگاه آزاد اسلامی، تهران، ایران، کد پستی: 1913674711

4 گروه شیمی کاربردی، دانشکده شیمی دارویی، دانشگاه علوم پزشکی تهران، دانشگاه آزاد اسلامی، تهران، ایران، کد پستی: 1913674711

چکیده

در این مقاله از سه جاذب مغناطیسی شامل polyaniline@NiFe2O4، polyaniline@MgFe2O4 و polyaniline@MnFe2O4 به منظور حذف آلاینده‌ی رنگی قرمز کنگو استفاده شده است. نانوجاذب‌های سنتز شده توسط روش‌های مختلفی از جمله میکروسکوپ الکترونی روبشی، پراش اشعه ایکس، پراش انرژی پرتو ایکس و طیف‌سنجی زیر قرمز شناسایی شدند. سپس عوامل موثر بر بازده حذف قرمز کنگو در مورد هر سه جاذب بهینه‌سازی شد. در شرایط بهینه بازده حذف قرمز کنگو از محیط آبی توسط polyaniline@MgFe2O4، polyaniline@MnFe2O4 و polyaniline@NiFe2O4، به ترتیب برابر با 92، 90 و 89 درصد محاسبه شد. امکان احیا و بازیابی نانوکامپوزیت‌های مورد استفاده بررسی شد و اسیدکلریدریک 1 مولار به عنوان عامل بازیابی‌کننده توانست تا 4 مرتبه هر سه نانوکامپوزیت را بازیابی کند. حذف قرمز کنگو از نمونه‌های حقیقی شامل آب چاه و پساب رنگرزی توسط جاذب‌های سنتز شده انجام گرفت. نتایج این بررسی نشان داد که پیچیدگی بافت بر کارایی نانوکامپوزیت‌ها اثر چشمگیری ندارد، بنابراین می‌توان از آن‌ها در نمونه‌های حقیقی با بافت پیچیده نیز برای حذف قرمز کنگو استفاده کرد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Synthesis, Characterization, and Adsorptive Properties of Polyaniline@MFe2O4 (M: Mg, Mn, Ni) Magnetic Nanocomposites

نویسندگان [English]

  • M. Zare 1
  • E. Adibian 2
  • E. Ghasemi 3
  • F. Ashouri 4
1 Basic Sciences Group, Golpayegan College of Engineering, Isfahan University of Technology, P.O. Box: 87717-67498, Golpayegan, Iran
2 Drug Delivery System Research Center, Tehran Medical Sciences, Islamic Azad University, P.O. Code: 1941933111, Tehran, Iran
3 Department of Pharmaceutical Chemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, P.O. Code: 1913674711, Tehran, Iran
4 Department of Applied Chemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, P.O. Code: 1913674711, Tehran, Iran
چکیده [English]

This paper used three magnetic adsorbents, including polyaniline@NiFe2O4, polyaniline@MgFe2O4, and polyaniline@MnFe2O4 to remove congo red dye. The synthesized nanocomposites were identified using SEM, XRD, EDX, and FT-IR methods. Then the factors affecting the removal efficiency of congo red were optimized for all three adsorbents. Under optimum conditions, the removal efficiencies of congo red from aqueous media by polyaniline@NiFe2O4, polyaniline@MgFe2O4, and polyaniline@MnFe2O4 were calculated as 92, 90 and

89 %, respectively. The reusability of the used nanocomposites was investigated, so 1 M HCl as a recovery agent could recover up to 4 times all three nanocomposites. The synthesized sorbents performed the removal of congo red from real samples, including well water and dyeing wastewater. The results showed that the matrix does not significantly affect the efficiency of the nanocomposites so that they could be used in real samples with complex matrices.

کلیدواژه‌ها [English]

  • Congo Red
  • Magnetic Nanoparticles
  • Polyaniline@MnFe2O4
  • Polyaniline@NiFe2O4
  • Polyaniline@MgFe2O4

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