سنتز کیتوسان مغناطیسی شبکه‌ای شده برای حذف مقادیر کم برخی فلزات سنگین از محلول‌های آبی

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه آزاد اسلامی واحد ورامین(پیشوا)، ایران، صندوق پستی: 74895-33817

چکیده

مقادیر کم مس (II) و سرب (II) با استفاده از یک نانوجاذب زیستی جدید براساس دانه‌های مغناطیسی کیتوسان شبکه‌ای شده اصلاح شده با پایه متیونین-گلوتارآلدهید شیف باز(MG-Chi/Fe3O4)  در نمونه‌های فاضلاب حذف شدند. طیف تبدیل فوریه زیر قرمز (FTIR)، پراش پرتو ایکس(XRD)  و میکروسکوپ الکترونی روبشی(SEM)  برای شناسایی نانو بیو ذرات استفاده شدند. عوامل مختلف مؤثر بر رفتارهای جذب یون‌های فلزی از جمله pH، مقدار جاذب، زمان تماس و غلظت اولیه یون‌های فلزی مورد بررسی و بهینه‌سازی قرار گرفتند. برای پیش‌بینی مدل جذب از مدل‌های ایزوترم فروندلیچ و لانگمویر استفاده شد. داده‌های تعادل با مدل ایزوترم لانگمویر به خوبی متناسب بودند. بیشینه ظرفیت جذب برای مس (II) و سرب (II) به ترتیب 172.4 و 175.4 میلی گرم در گرم بود. سینتیک جذب با مدل شبه مرتبه دوم مطابقت بهتری داشت. سرانجام این روش برای حذف هم‌زمان مس (II) و سرب (II) در نمونه‌های فاضلاب صنعتی با موفقیت استفاده شد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Synthesis of Crosslinked Magnetic Chitosan to Removal of Trace Amounts of Some Heavy Metals from Aqueous Solutions

نویسندگان [English]

  • N. Salehi
  • A. Moghimi
Department of Chemistry, Varamin (Pishva) Branch, Islamic Azad University, P.O. Box: 33817-74895, Varamin, Iran
چکیده [English]

Trace amounts of Cu (II) and Pb (II) in the wastewater sample were removed with a new nano biosorbent based on cross-linked chitosan magnetic beads modified with methionine-glutaraldehyde Schiff's base (MG-Chi/Fe3O4) in wastewater samples. Fourier transform infrared spectra (FTIR), X-ray diffraction (XRD) analysis, and scanning electron microscope (SEM) have been applied to characterize nano biosorbent. Various parameters affecting the uptake behavior of the metal ions were examined and optimized, including pH, adsorbent dose, contact time, and initial concentration. Freundlich and Langmuir isotherm models were applied to estimate adsorption mode. The equilibrium data were well fitted with the Langmuir isotherm model. The maximum adsorption capacities for Cu (II) and Pb (II) were 172.4 and 175.4 mg g-1, respectively. The adsorption kinetics are better consistent with the pseudo-second-order model. It was concluded that this method was successfully applied for the simultaneous removal of Cu (II) and Pb (II) in industrial wastewater samples.

کلیدواژه‌ها [English]

  • Magnetic chitosan
  • Removal of metal ions
  • Cross-linking
  • Adsorbance

مراجع

  1. Maleki, E. Pajootan, B. Hayati, Ethylacrylate grafted chitosan for heavy metal removal from wastewater: Equilibrium, kinetic and thermodynamic studies. J. Taiwan Inst. Chem. Eng. 51(2015), 127–134.
  2. Y. G. Abou El-Reash, M. Otto, I. M. Kenawy, A. M. Ouf, Adsorption of Cr(VI) and As(V) ions by modified magnetic chitosan chelating resin. Int. J. Biol. Macromol. 49(2011), 513– 522.
  3. Wang, Y. Zhu, Z. Bai, R. Luque, J. Xuan, Functionalized chitosan biosorbents with ultra-high performance, mechanical strength and tunable selectivity for heavy metals in wastewater treatment. Chem. Eng. J. 325(2017), 350–359.
  4. X. Luo, J. Zeng, S. Liu, L. Zhang, An effective and recyclable adsorbent for the removal of heavy metal ions from aqueous system: Magnetic chitosan/cellulose microspheres. Bioresource Technol. 194 (2015), 403–406.
  5. Y. G. Abou El-Reasha, Magnetic chitosan modified with cysteine-glutaraldehyde as adsorbent for removal of heavy metals from water. J. Environ. Chem. Eng. 4(2016), 3835–3847.
  6. M. Abniki, A. Moghim, Removal and Measurement of Bromocresol Purple Dye in Aqueous Samples by βCyclodextrin-Modified Magnetic Carbon Nanotube with Dispersive Solid-Phase Extraction Technique. Color Sci. Tech. 15(2022), 301-315.
  7. Y. Wang, Y. Zhang, C. Hou, M. Liu, Mussel-inspired synthesis of magnetic polydopamine–chitosan nanoparticles as biosorbent for dyes and metals removal. J. Taiwan Institute Chem. Eng. 61(2016), 292-298.
  8. K. Yu, J. Ho, E. McCandlish, B. Buckley, R. Patel, Z.B. Li, N. C. Shapley, Copper ion adsorption by chitosan nanoparticles and alginate microparticles for water purification applications. Colloid Surf. A. 425(2013), 31-34.
  9. Maleki, E. Pajootan, B. Hayati, Ethyl acrylate grafted chitosan for heavy metal removal from wastewater: Equilibrium, kinetic and thermodynamic studies. Taiwan Institute Chem. Eng. 51(2015), 127-134.
  10. M. Ahmaruzzaman, S. L. Gayatri, Activated tea waste as a potential low-cost adsorbent for the removal of p-nitrophenol from wastewater. J. Chem. Eng. Data. 55(2010), 4614-4623.
  11. H. R. Tashauoei, H. Movahedian, H. Attar, M. M. Amin, M. Kamali, M. Nikaeen, V. M. Dastjerdi, Removal of cadmium and humic acid from aqueous solutions using surface modified nanozeolite. Inter J. Environ. Sci. Technol. 7(2010), 497-508.
  12. Z. C. Wu, Z. Z. Wang, J. Liu, S. P. Kuang, Removal of Cu(II) ions from aqueous water by l-arginine modifyingmagnetic chitosan. Colloids Surf. A. 499(2016), 141–149.
  13. Y. Xiao, X. Zhou, Synthesis and properties of a novel crosslinked chitosan resin modified by l-lysine. React Funct Polym. 68(2008), 1281-1289.
  14. M. V. Dinu, E. S. Dragan, Evaluation of Cu2+, Co2+ and Ni2+ ions removal from aqueous solution using a novel chitosan/clinoptilolite composite: kinetics and isotherms. Chem Eng J. 160(2010), 157–163.
  15. S. A. Ali, M. A. J. Mazumder, A new resin embedded with chelating motifs of biogenic methionine for the removal of Hg(II) at ppb levels, J. Hazar Mater. 350(2018), 169-179.
  16. H. S. Ibrahim, N. S. Ammar, M. Soylak, M. M. Ibrahim, Removal of Cd(II) and Pb(II) from aqueous solution using dried water hyacinthas a biosorbent. Spectrochim Acta A . 96(2012), 413–420.
  17. L. Ma, Y. Peng, B. Wu, D. Lei, H. Xu, Pleurotus ostreatus nanoparticles as a new nano-biosorbent for removal of Mn(II) from aqueous solution, Chem. Eng. J. 225(2013), 59–67.
  18. D. Ozdes, A. Gundogdu, B. Kemer, C. Duran, H. B. Senturk, M. Soylak, Removal of Pb(II) ions from aqueous solution by a waste mud from copper mine industry: Equilibrium, kinetic and thermodynamic study, J. Hazard Mater. 166(2009), 1480–1487.
  19. J. R. Rangel-Mendez, R. Monroy-Zepeda, E. Leyva-Ramos, P. E. Diaz-Flores, Chitosan selectivity for removing cadmium(II), copper(II), and lead(II) from aqueous phase: pH and organic matter effect, J. Hazard Mater. 162(2009), 503–511.
  20. N. N Salehi, A Moghimi, H Shahbazi, Preparation of cross-linked magnetic chitosan with methionine-glutaraldehyde for removal of heavy metals from aqueous solutions, J. Environ. Anal Chem. (2020), 1-17.
  21. M. Faraji, Y. Yamini, E. Tahmasebi, A. Saleh, Nourmohammadian, F. Cetyltrimethylammonium bromide-coated magnetite nanoparticles as highly efficient adsorbent for rapid removal of reactive dyes from the textile companies wastewaters, JICS, 7(2010), S130.
  22. M. Adeli, Y. Yamini, M. Faraji, Removal of copper, nickel and zinc by sodium dodecyl sulphate coated magnetite nanoparticles from water and wastewater samples. Arabian J. Chem. 10: S514 (2017).
  23. M. R. Yarandpour, A. Rashidi, R. Khajavi, N. Eslahi, M. E. Yazdanshenas, Preparation of Polyacrylic Acid (PAA) / Dextran Nanofibres Modified with Aniline to the Removal of Metal (Pb) from Aqueous Solutions, J. Color Sci. Tech. 14(2021), 255-271.
  24. N. Salehi, A. Moghimi, H., Shahbazi, Magnetic nano biosorbent (MG-Chi/Fe3O4) for dispersive solid phase extraction of Cu(II), Pb(II) and Cd(II) followed by FAAS determination. IET Nanobiotechnol. (2021)
  25. A. Moghimi, M. Abniki, The Dispersive Solid-Phase Extraction of Fluoxetine Drug from Biological Samples by the Amine-Functionalized Carbon Nanotubes with HPLC Method. Chem. Methodol. 5(2021), 250-258.
  26. Sh. Eyvazi, M. Shabani, A. Moghimi, The Modification of Carboxylated Multi-Walled Carbon Nanotube Using Titanium Dioxide for Surface Adsorption of Indigo Carmine Dye From Aqueous Environment (Thermodynamics and Kinetics Study), J. Color Sci. Tech. 15(2021), 13- 28.
  27. A. Ramesh, H. Hasegawa, Sugimoto, W. Maki, T. K. Ueda, Adsorption of gold(III), platinum(IV) and palladium(II) onto glycine modified crosslinked chitosan resin, Bioresour Technol. 99(2008), 3801-3809.

فایل ها

هم رسانی

ارجاع به این مقاله

آمار