بررسی عملکرد بازدارندگی خوردگی عصاره آبی دارچین روی فولاد ساده کربنی در محیط اسید هیدروکلریک 1 مولار

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه گلستان، علی‌آباد کتول، ایران

2 گروه پوشش‌های سطح و خوردگی، پژوهشگاه رنگ، تهران، ایران

چکیده

بازدارنده‌های خوردگی یک روش آسان و اقتصادی جهت کنترل خوردگی فلزات در محیط‌های اسیدی می‌باشد. در این راستا بازدارنده‌های خوردگی سبز بر پایه عصاره گیاهان به‌عنوان یک جایگزین مناسب بازدارنده‌های خوردگی سنتزی رایج که عمدتاً دوست‌دار محیط‌زیست نمی‌باشند مورد توجه فراوان قرار گرفته است. حضورترکیبات فعال درعصاره آبی دارچین آن را به‌ یک منبعی از بازدارنده‌های سبز در کنترل خوردگی فولاد تبدیل کرده است. در این مطالعه عملکرد بازدارندگی عصاره دارچین توسط آزمون‌های الکتروشیمیایی و روش‌های تحلیل سطحی مورد بررسی قرار گرفت. نتایج طیف‌سنجی امپدانس الکتروشیمیایی نشان داد که پس از 2.5 ساعت غوطه‌وری فولاد در محلول 1 مولار اسید هیدروکلریکحاوی ppm 800عصاره دارچین،بازده بازدارندگی خوردگی 88% به دست آمد. علاوه­بر­این، نتایج حاصل از آزمون پلاریزاسیون پتانسیودینامیک کاهش چشمگیر چگالی جریان خوردگی و نرخ واکنش‌های آندی و کاتدی را نشان داد. تصاویر میکروسکوپی الکترونی و اتمی، تخریب کم سطح فلز که بیانگر تشکیل لایه محافظ بازدارنده روی سطح فولاد است را نشان دادند. هم‌چنین جذب بازدارنده بر روی سطح از ایزوترم جذب لانگمویر پیروی نمود.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Studying the Inhibition Action of Aqueous Extract of Cinnamomum Verum for Carbon Steel in 1 M HCl Solution

نویسندگان [English]

  • A. Dehghani 1
  • Gh. Bahlakeh 1
  • B. Ramezanzadeh 2
1 Department of Chemical Engineering, Faculty of Engineering, Golestan University,Aliabad Katoul, Iran
2 Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, Tehran, Iran
چکیده [English]

Corrosion inhibitors are a simple and economic method for corrosion control of metals in acidic environments. In this regard, green corrosion inhibitors based on plant extracts have received much attention as a suitable replacement to the synthetic and environmentally unsafe inhibitors. The presence of various active compounds in the aqueous extract of Cinnamomum Verum converted it to a rich source of green inhibitors for steel corrosion control. In this study, the inhibition action of Cinnamomum Verum extract was evaluated by electrochemical and surface analysis methods. The electrochemical impedance spectroscopy (EIS) results demonstrated that after 2.5 h steel immersion in 1 M HCl solution containing 800 ppm inhibitor 88% inhibition efficiency was obtained. In addition, the potentiodynamic polarization results indicated the significant reduction of corrosion current density, anodic and cathodic reactions rates. The images of scanning electron microscopy and atomic force microscopy evidenced the lower steel surface damage, indicating formation of inhibitor film over the steel surface. Furthermore, the inhibitor adsorption obeyed the Langmuir adsorption isotherm.

کلیدواژه‌ها [English]

  • Carbon steel
  • corrosion
  • green inhibitor
  • potentiodynamic polarization
  • EIS
  • SEM
A. Abbas, É. Fazakas, T. Török, Corrosion studies of steel rebar samples in neutral sodium chloride solution also in the presence of a bio-based (green) inhibitor. Int. J. Corros. Scale Inhib. 7(2018), 38-47.
S. About, M. Chellouli, M. Zouarhi, B. Benzidia, H. Hammouch, D. Chebabe, A. Dermaj, H. Erramli, N. Bettach, N. Hajjaji, New formulation based on ceratonia siliqua L seed oil, as a green corrosion inhibitor of iron in acidic medium. Anal. Bioanal. Chem. 10(2018), 789-804.
F. E. Abeng, V. D. Idim, Green corrosion inhibitor for mild steel in 2 M HCl solution: Flavonoid extract of frigeron floribundus. World Sci. News. 98(2018), 89-99.
L. Afia, R. Salghi, A. Zarrouk, H. Zarrok, E. H. Bazzi, B. Hammouti, M. Zougagh, Comparative study of corrosion inhibition on mild steel in HCl medium by three green compounds: Argania spinosa press cake, kernels and hulls extracts. Trans. Indian. Inst. Met. 66(2013), 43-49.
K. M. Al-Ahmary, R. A. Mekheimer, M. S. Al-Enezi, N. M. Hamada, M. M. Habeeb, Synthesis, spectrophotometric characterization and DFT computational study of a novel quinoline derivative, 2-amino-4-(2, 4, 6-trinitrophenylamino)-quinoline-3-carbonitrile. J. Mol. Liq. 249(2018), 501-510.
M. T. Alhaffar, S. A. Umoren, I. B. Obot, S. A. Ali, Isoxazolidine derivatives as corrosion inhibitors for low carbon steel in HCl solution: experimental, theoretical and effect of KI studies. RSC Adv. 8(2018), 1764-1777.
E. Alibakhshi, M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, M. Mahdavian, M. Motamedi, Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study. J. Mol. Liq. 255(2018), 185-198.
M. Banu, R. Joany, S. Rajendran, Green approach to corrosion inhibition of mild steel in acid medium by aqueous extract of pedalium murex L. leaves. Der. Pharma. Chemica. 10(2108), 21-28.
K. Kalaiselvi, I.-M. Chung, S.-H. Kim, M. Prabakaran, Corrosion resistance of mild steel in sulphuric acid solution by coreopsis tinctoria extract: electrochemical and surface studies. Anti. Corros. Method. M. 65(2018), 408-416.
H. Bourazmi, M. Tabyaoui, L. Hattabi, Y. El Aoufir, M. Taleb, Methanolic extract of salvia officinalis plant as a green inhibitor for the corrosion of carbon steel in 1 M HCl. J. Mat. Environ. Sci. 9(2018), 928-938.
J. Stephen, A. Adebayo, Inhibition of corrosion of mild steel in hydrochloric acid solution using akee apple seed extract. J. Fail. Analys. Prevent. 18(2018), 350-355.
D. K. Verma, F. Khan, I. Bahadur, M. Salman, M. A. Quraishi, C. Verma, E. E. Ebenso, Inhibition performance of glycine max, cuscuta reflexa and spirogyra extracts for mild steel dissolution in acidic medium: Density functional theory and experimental studies. Resul. Phy. 10(2018), 665-674.
T. J. Zachariah, N. K. Leela, 11 - Volatiles from herbs and spices, in: K.V. Peter (Ed.) Handbook of herbs and spices. Woodhead Publishing. 2006, 177-218.
H. Bourazmi, M. Tabyaoui, L. Hattabi, Y. El Aoufir, E. Ebenso, A. Ansari, Camphor as an effective corrosion inhibitor for carbon steel in 1M HCl solution: electrochemical and quantum chemical investigation. J. Mat. Environ. Sci. 9(2018), 1058-1074.
A. Brevik, I. Gaivão, T. Medin, A. Jørgenesen, A. Piasek, J. Elilasson, A. Karlsen, R. Blomhoff, T. Veggan, A. K. Duttaroy, Supplementation of a western diet with golden kiwifruits (Actinidia chinensis var.'Hort 16A':) effects on biomarkers of oxidation damage and antioxidant protection. Nut. J. 10(2011), 54-65.
S. Zehra, M. Mobin, J. Aslam, M. Parveen, Assessment of glycine derivative N-benzylidine-2 ((2-oxo-2-(10H-phenothiazine-10yl) ethyl) amino) acetohydrazide as inhibitor for mild steel corrosion in 1 M HCl solution: electrochemical and theoretical approach. J. Adhes. Sci. Technol. 32(2018), 317-342.
K. Zhang, W. Yang, X. Yin, Y. Chen, Y. Liu, J. Le, B. Xu, Amino acids modified konjac glucomannan as green corrosion inhibitors for mild steel in HCl solution. Carbohyd. Polym. 181(2018), 191-199.
M. Tezeghdenti, N. Etteyeb, L. Dhouibi, O. Kanoun, Sustainable use of natural resources as alternative for the hazardous corrosion inhibitor of mild steel/dilute sulfuric acid interface: Weight Loss, EIS, AFM and FTIR studies. Arch. Metall. Mater. 63(2018), 697-707.
S. A. Haladu, S. A. Umoren, S. A. Ali, M. M. Solomon, A.-R. I. Mohammed, Synthesis, characterization and electrochemical evaluation of anticorrosion property of a tetrapolymer for carbon steel in strong acid media. Chin. J. Chem. Eng. 10(2018), 31-45.
K. Kalaiselvi, I. M. Chung, S. H. Kim, M. Prabakaran, Corrosion resistance of mild steel in sulphuric acid solution by coreopsis tinctoria extract: electrochemical and surface studies. Anti-Corros. Method. M. 65(2018), 408-416.
S. Chen, D. Zhang, Study of corrosion behavior of copper in 3.5 wt.% NaCl solution containing extracellular polymeric substances of an aerotolerant sulphate-reducing bacteria. Corros. Sci. 136(2018), 275-284.
M. A. Chidiebere, E. E. Oguzie, L. Liu, Y. Li, F. Wang, Corrosion inhibition of Q235 mild steel in 0.5 M H2SO4 solution by phytic acid and synergistic iodide additives. Ind. Eng. Chem. Res. 53(2014), 7670-7679.
J. Cui, Y. Yang, X. Li, W. Yuan, Y. Pei, Toward a slow-release borate inhibitor to control mild steel corrosion in simulated recirculating water. ACS Appl. Mater. Inter. 10(2018), 4183-4197.
D. Debnath, A. K. Gupta, Optimizing the fabrication of nano-plasmonic silver‑nitrogen co-doped zinc oxide (AgxZn (1-x) NyO (1-y)) mediated by ammonia template: Insight into its enhanced physiochemical and photocatalytic behavior. J. Mol. Liq. 249(2018), 334-345.
J. Ding, B. Tang, M. Li, X. Feng, F. Fu, L. Bin, S. Huang, W. Su, D. Li, L. Zheng, Difference in the characteristics of the rust layers on carbon steel and their corrosion behavior in an acidic medium: Limiting factors for cleaner pickling. J. Clean. Prod.142(2017), 2166-2176.
P. Dohare, D. Chauhan, A. Sorour, M. Quraishi, DFT and experimental studies on the inhibition potentials of expired Tramadol drug on mild steel corrosion in hydrochloric acid. Mater. Discov. 9(2017), 30-41.
A. Döner, R. Solmaz, M. Özcan, G. Kardaş, Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corros. Sci. 53(2011), 2902-2913.
M. El-Deeb, N. Abdel-Shafi, A. Shamroukh, Electrochemical, DFT and mont carlo simulations studies to evaluate the inhibition effect of novel pyridazine derivatives on iron pitting corrosion in 3.5% NaCl. Int. J. Electrochem. Sci. 13(2018), 5352-5369.
A. El-Etre, A. Ali, A novel green inhibitor for C-steel corrosion in 2.0 mol L-1 hydrochloric acid solution. Chinese J. Chem. Eng. 25(2017), 373-380.
F. El-Hajjaji, M. Belghiti, B. Hammouti, S. Jodeh, O. Hamed, H. Lgaz, R. Salghi, Adsorption and corrosion inhibition effect of 2-mercaptobenzimidazole (surfactant) on a carbon steel surface in an acidic medium: Experimental and monte carlo simulations. Port. Electrochim. Acta. 36(2018), 197-212.
G. D. Eyu, G. Will, W. Dekkers, J. MacLeod, The synergistic effect of iodide and sodium nitrite on the corrosion inhibition of mild steel in bicarbonate–chloride solution. Mater. 9(2016), 868-882.
H. Ezuber, A. Alshater, S. Nisar, A. Gonsalvez, S. Aslam, Effect of surface finish on the pitting corrosion behavior of sensitized aisi 304 austenitic stainless steel alloys in 3.5% NaCl solutions. Surf. Eng. Appl. Electrochem. 54(2018), 73-80.
A. A. Farag, A. S. Ismail, M. Migahed, Environmental-friendly shrimp waste protein corrosion inhibitor for carbon steel in 1 M HCl solution. Egypt. J. Pet. 27(2018), 1187-1194.
R. Farahmand, B. Sohrabi, A. Ghaffarinejad, M. R. Z. Meymian, Synergistic effect of molybdenum coating and SDS surfactant on corrosion inhibition of mild steel in presence of 3.5% NaCl. Corros. Sci. 136(2018), 393-401.
A. Fawzy, M. Abdallah, I. A. Zaafarany, S. A. Ahmed, I. I. Althagafi, Thermodynamic, kinetic and mechanistic approach to the corrosion inhibition of carbon steel by new synthesized amino acids-based surfactants as green inhibitors in neutral and alkaline aqueous media. J. Mol. Liq. 265(2018), 276-291.
L. Feng, S. Zhang, Y. Qiang, S. Xu, B. Tan, S. Chen, The synergistic corrosion inhibition study of different chain lengths ionic liquids as green inhibitors for X70 steel in acidic medium. Mater. Chem. Phys. 215(2018), 229-241.
A. Fouda, G. El-Awady, W. El Behairy, Prosopis juliflora plant extract as potential corrosion inhibitor for low-carbon steel in 1 M HCl solution. J. Bio-and Tribo-Corros. 4(2018), 1-12.
H. Gerengi, M. M. Solomon, M. Kurtay, G. Bereket, K. Goksen, M. Yıldız, E. Kaya, Electrochemical and morphological assessments of inhibition level of 8-hydroxylquinoline for AA2024-T4 alloy in 3.5% NaCl solution. J. Adhes. Sci. Technol. 32(2018), 207-223.
A. Ghames, T. Douadi, S. Issaadi, L. Sibous, K. I. Alaoui, M. Taleb, S. Chafaa, Theoretical and experimental studies of adsorption characteristics of newly synthesized schiff bases and their evaluation as corrosion inhibitors for mild steel in 1 M HCl. Int. J. Electrochem. Sci. 12(2017), 4867-4897.
P. B. Matad, P. B. Mokshanatha, N. Hebbar, V. T. Venkatesha, H. C. Tandon, Ketosulfone drug as a green corrosion inhibitor for mild steel in acidic medium. Ind. Eng. Chem. Res. 53(2014), 8436-8444.
X. Zheng, S. Zhang, M. Gong, W. Li, Experimental and theoretical study on the corrosion inhibition of mild steel by 1-octyl-3-methylimidazolium L-prolinate in sulfuric acid solution. Ind. Eng. Chem. Res. 53(2014), 16349-16358.
Z. Tao, S. Zhang, W. Li, B. Hou, Adsorption and corrosion inhibition behavior of mild steel by one derivative of benzoic- triazole in acidic solution. Ind. Eng. Chem. Res. 49(2010), 2593-2599.
A. K. Singh, Inhibition of mild steel corrosion in hydrochloric acid solution by 3-(4-((Z)-indolin-3-ylideneamino) phenylimino) indolin-2-one. Ind. Eng. Chem. Res. 51(2012), 3215-3223.
P. M. Krishnegowda, V. T. Venkatesha, P. K. M. Krishnegowda, S. B. Shivayogiraju, Acalypha torta leaf extract as green corrosion inhibitor for mild steel in hydrochloric acid solution. Ind. Eng. Chem. Res. 52(2013), 722-728.
D. Gopi, E.-S. M. Sherif, V. Manivannan, D. Rajeswari, M. Surendiran, L. Kavitha, Corrosion and corrosion inhibition of mild steel in groundwater at different temperatures by newly synthesized benzotriazole and phosphono derivatives. Ind. Eng. Chem. Res. 53(2014), 4286-4294.
M. Benghalia, C. Fares, A. Khadraoui, M. H. Meliani, I. Obot, A. Sorrour, M. Dmytrakh, Z. Azari, Performance evaluation of a natural and synthetic compound as corrosion inhibitors of API 5L X52 steel in hydrochloric acid media. Mor. J. Chem.6(2018), 51-61.
R. Idouhli, A. N’Ait Ousidi, Y. Koumya, A. Abouelfida, A. Benyaich, A. Auhmani, M. Y. Ait Itto, Electrochemical studies of monoterpenic thiosemicarbazones as corrosion inhibitor for steel in 1 M HCl. Int. J. Corros. 2018(2018), 1-14